Methoxycarbonylation of Styrene Using a New Type of Palladium Complexes Bearing P,N-donor Ligands as Catalysts
| Author | dc.contributor.author | Abarca, Gabriel | |
| Author | dc.contributor.author | Brown, Kareen | |
| Author | dc.contributor.author | Moya, Sergio A. | |
| Author | dc.contributor.author | Bayón, J. Carles | |
| Author | dc.contributor.author | Aguirre Álvarez, Pedro | |
| Admission date | dc.date.accessioned | 2015-10-01T20:29:29Z | |
| Available date | dc.date.available | 2015-10-01T20:29:29Z | |
| Publication date | dc.date.issued | 2015 | |
| Cita de ítem | dc.identifier.citation | Catalysis Letters (2015) 145:1396–1402 | en_US |
| Identifier | dc.identifier.other | DOI: 10.1007/s10562-015-1502-y | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/134048 | |
| General note | dc.description | Artículo de publicación ISI | en_US |
| Abstract | dc.description.abstract | Palladium complexes of the type [Pd(L)Cl(PPh3)]Cl (L = 2-diphenylphosphinoamino)pyrimidine, or 2-diphenylphosphinoaniline), generated in situ by addition of one equivalent of PPh3 to the corresponding neutral complexes [Pd(L)Cl-2], were tested as catalysts for the methoxycarbonylation of styrene. The catalyst containing the pyrimidinyl ligand shows almost complete chemo- and regioselectivity together with a high conversion rate. However, in identical conditions, the [Pd(Ph2PNHC6H4PPh2)Cl-2] complex, where the P,N-ligand has been replaced by a related bidentate P-donor one, shows a significantly lesser performance. | en_US |
| Patrocinador | dc.description.sponsorship | Fondecyt-Chile 1120149 | en_US |
| Lenguage | dc.language.iso | en | en_US |
| Publisher | dc.publisher | Springer | en_US |
| Type of license | dc.rights | Atribución-NoComercial-SinDerivadas 3.0 Chile | * |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | * |
| Keywords | dc.subject | Palladium catalyst | en_US |
| Keywords | dc.subject | Phosphorus nitrogen ligand | en_US |
| Keywords | dc.subject | Methoxycarbonylation | en_US |
| Keywords | dc.subject | Styrene | en_US |
| Keywords | dc.subject | Homogeneous catalysis | en_US |
| Título | dc.title | Methoxycarbonylation of Styrene Using a New Type of Palladium Complexes Bearing P,N-donor Ligands as Catalysts | en_US |
| Document type | dc.type | Artículo de revista |
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Except where otherwise noted, this item's license is described as Atribución-NoComercial-SinDerivadas 3.0 Chile