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A dense hydrogen-bonding network and an unusually large packing index in triaquatris(2,4-dioxo-1,2,3,4-tetrahydropyrimidine- 5-carboxylato)neodymium(III) trihydrate

Authordc.contributor.authorAtria Salas, Ana María 
Authordc.contributor.authorGarland, María Teresa 
Authordc.contributor.authorBaggio, Ricardo 
Admission datedc.date.accessioned2016-04-24T22:31:57Z
Available datedc.date.available2016-04-24T22:31:57Z
Publication datedc.date.issued2013
Cita de ítemdc.identifier.citationActa Cryst. (2013). C69, 1378–1382en_US
Identifierdc.identifier.issn0108-2701
Identifierdc.identifier.urihttp://repositorio.uchile.cl/handle/2250/137934
Abstractdc.description.abstractThe title mononuclear complex, [Nd(C5H3N2O3)3(H2O)3] - 3H2O, consists of an NdIII cation, three 2,4-dioxo-1,2,3,4- tetrahydropyrimidine-5-carboxylate ligands and three aqua ligands forming the neutral complex molecule, and three solvent water molecules. The pyrimidinecarboxylate ligands act in a chelating manner, via carboxylate and keto O atoms. The NdO9 coordination polyhedron is in the form of a distorted monocapped square antiprism. The availability of numerous hydrogen-bonding donors and acceptors results in a very dense hydrogen-bonding network, the immediate effect of which is an unusually large packing index.en_US
Lenguagedc.language.isoenen_US
Type of licensedc.rightsAtribución-NoComercial-SinDerivadas 3.0 Chile*
Link to Licensedc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/*
Keywordsdc.subjectCrystal structureen_US
Keywordsdc.subjectMononuclear neodymium complexen_US
Keywordsdc.subjectComplex hydrogen-bonding networken_US
Keywordsdc.subjectDensely packed structureen_US
Títulodc.titleA dense hydrogen-bonding network and an unusually large packing index in triaquatris(2,4-dioxo-1,2,3,4-tetrahydropyrimidine- 5-carboxylato)neodymium(III) trihydrateen_US
Document typedc.typeArtículo de revistaen_US


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Atribución-NoComercial-SinDerivadas 3.0 Chile
Except where otherwise noted, this item's license is described as Atribución-NoComercial-SinDerivadas 3.0 Chile