Vibrational analysis of metal diimine dithiolate mixed ligand complexes
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1999Metadata
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Díaz, Guillermo
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Vibrational analysis of metal diimine dithiolate mixed ligand complexes
Abstract
The IR spectra of the M(mnt)(baba) where M = Ni and Pd, mnt = 1,2-maleonitrile and baba = biacetylbisanyline, were recorded in the high as well in the low energy region. A complete assignment of the observed bands was performed based on well-documented references. Further, a normal coordinate analysis was carried out taking into account C2υ symmetry, and based in a simplified model in order to investigate the force field of both metal complexes and the potential energy distribution (PED) of the distinct modes of the quelate structure. © 1999 Elsevier Science B.V. All rights reserved.
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URI: https://repositorio.uchile.cl/handle/2250/156780
DOI: 10.1016/S1386-1425(98)00239-X
ISSN: 13861425
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Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Volumen 55, Issue 5, 2018, Pages 979-990
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