Reactivity of chromium(III) and cobalt(III) acetylacetonato complexes
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A comparative study of the ligand reactivity at the 3-position in trisacetylacetonates of Cr(III) and Co(III), by means of nitration and Vilsmeier-Haack reactions, was attempted. The sequence Co > Cr in both reactions was found. Hückel calculations of reactivity indices were performed and theoretical reactivity results agreed with experiment. © 1971.
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