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Authordc.contributor.authorBaraona, Ruth 
Authordc.contributor.authorRozenblum, Sylvia 
Authordc.contributor.authorZamudio, Walter 
Admission datedc.date.accessioned2018-12-20T15:10:03Z
Available datedc.date.available2018-12-20T15:10:03Z
Publication datedc.date.issued1978
Cita de ítemdc.identifier.citationJournal of Inorganic and Nuclear Chemistry, Volumen 40, Issue 12, 2018, Pages 2043-2047
Identifierdc.identifier.issn00221902
Identifierdc.identifier.other10.1016/0022-1902(78)80200-0
Identifierdc.identifier.urihttps://repositorio.uchile.cl/handle/2250/158120
Abstractdc.description.abstractKinetic studies of the [Co(phen)3] (ClO4)3 2H2O nitromethane pyridine reaction were made spectrophotometrically, by recording the appearance of a new absorption band at 474 nm. The reaction is first order with respect to all three reactants. Reaction products were isolated and attempts were made to purify them. A mechanism is proposed for the reaction involving the formation of Co(phen)33+CH2NO2- (ClO4)2. The rate determining step would be the rupture of a CH bond in the solvated nitromethane molecule. © 1978.
Lenguagedc.language.isoen
Type of licensedc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
Link to Licensedc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
Sourcedc.sourceJournal of Inorganic and Nuclear Chemistry
Títulodc.titleReaction of tris(1,10-phenanthroline) cobalt(III) perchlorate, nitromethane and an excess of base-I reaction with pyridine
Document typedc.typeArtículo de revista
Catalogueruchile.catalogadorSCOPUS
Indexationuchile.indexArtículo de publicación SCOPUS
uchile.cosechauchile.cosechaSI


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