Browsing by Author "201-0010752"
Now showing items 1-20 of 68
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Heredia Moya, Jorge; Krohn, Karsten; Florke, Ulrich; Araya Maturana, Ramiro (BLACKWELL PUBLISHING, 2006-09)(E)-Ethyl 3-(4-oxo-4H-chromen-3-yl)acrylate reacts in a Domino reaction with ethyl vinyl ether via intermediates to give the title bridged compound, C20H22O6, and by-products. The conformation of the carboxylate group in ...
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Boys Mardones, Daphne; Araya Maturana, Ramiro; Gonzáles Campos, Oscar Cesar; Manríquez Castro, Víctor (1995)The crystal structure of the title phosphonium salt consists of a tetrahedral (C6Hs)P +C(C4HS)- (COOCH2CH3) cation and a Br- anion. The triphenylphosphonium group has P---C(phenyl) distances which are equal within ...
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Donoso Tauda, Oscar; Escobar, Carlos A.; Araya Maturana, Ramiro; Vega, Andrés (BLACKWELL PUBLISHING, 2006-10)The molecule of the title compound, C19H20O2S, corresponds to a chiral sulfinyldienol with two stereogenic centres, viz. the C atom susbtituted by the hydroxy group and the sulfinyl S atom. The molecule displays a V-shape ...
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Araya Maturana, Ramiro; Heredia Moya, Jorge; Pessoa Mahana, Hernán; Weiss López, Boris; Muñoz, J. C. (BLACKWELL MUNKSGAARD, 2005-04)The title compound, C12H7NO3, consists of a chromone moiety substituted in position 3 with an acrylonitrile group in a Z configuration. The two planar groups are twisted with respect to one another. The only significant ...
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4-(2-Hydroxyphenyl)-2-phenyl-2,3-dihydro-1H-1,5-benzodiazepine and the 2-(2,3-dimethoxyphenyl)-, ... Escobar, C. A.; Donoso Tauda, Oscar; Araya Maturana, Ramiro; Vega, Andrés (BLACKWELL PUBLISHING, 2007-07)The 1,5-benzodiazepine ring system exhibits a puckered boatlike conformation for all four title compounds [4-(2-hydroxyphenyl)2- phenyl-2,3-dihydro-1H-1,5-benzodiazepine, C21H18N2O, (I), 2-(2,3-dimethoxyphenyl)-4-(2-hydr ...
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Vega, Andrés; Ramírez Rodríguez, Oney; Martínez Cifuentes, Maximiliano; Ibáñez, Andrés; Araya Maturana, Ramiro (WILEY-BLACKWELL PUBLISHING, INC, 2009-02)The title molecule, C14H14O3, contains two fused six-membered carbon rings with keto groups at positions 1, 4 and 5 and a gem-diethyl group at position 8. The molecule is close to planar (maximum deviation = 0.044 angstrom), ...
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Ramírez Rodríguez, Oney; Martínez Cifuentes, Maximiliano; Ibáñez, A.; Vega, Andrés; Araya Maturana, Ramiro (BLACKWELL PUBLISHING, 2008-07)In the title molecule, C16H16O3, the ring system is planar and an intramolecular hydrogen bond is present. The molecular packing is dominated by an intermolecular hydrogen bond and by pi-stacking interactions [interplanar ...
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Martínez Cifuentes, Maximiliano; Cardona, Wilson; Saitz Barría, Claudio; Weiss López, Boris; Araya Maturana, Ramiro (MDPI AG, 2017)A theoretical exploration about hydrogen bonding in a series of synthetic regioisomeric antitumor tricyclic hydroquinones is presented. The stabilization energy for the intramolecular hydrogen bond (IHB) formation in four ...
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Araya Maturana, Ramiro; Saitz Barría, Claudio; Pessoa Mahana, Hernán; Pessoa, D. (Bentham Science Publishers, 2003)The present review discusses the synthetic strategies of new ligands exhibiting mainly 5-HT1A binding affinities. Specifically we focused our attention in the synthesis of compounds structurally related to arylpiperazine, ...
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Ahumada, H.; Montecinos, R.; Martínez, R.; Araya Maturana, Ramiro; Weiss López, Boris (SOCIEDAD CHILENA DE QUIMICA, 2004-09)Deuterium quadrupole splittings, of deuterated water, Deltav, in anionic discotic nematic lyomesophases are always much larger than in cationic mesophases. To explore the possible origins of this difference, Deltav and T-1 ...
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Rodríguez Borges, Jorge; Olea Azar, Claudio; Cavieres, C.; Norambuena, Ester; Delgado Castro, Tomás; Soto Delgado, Jorge; Araya Maturana, Ramiro (PERGAMON-ELSEVIER SCIENCE LTD, 2007-11-15)This study was undertaken to investigate the free radical -scavenging and antioxidant activities of various structurally related hydroquinones including hydroxynaplithalenones and dihydroxyanthracenones. Electron spin ...
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Weiss López, Boris; Miño Galaz, Germán; Araya Maturana, Ramiro; Tracey, Alan S. (AMER CHEMICAL SOC, 2000-04-18)Deuterium quadrupole splittings of benzyl alcohol-d(5) and a series of alkyl benzyl-d(5), ethers, with linear aliphatic chains from 1 to 12 carbon atoms, were measured using H-2 NMR spectroscopy. These molecules were ...
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Weiss López, Boris; Saldaño Hurtado, Danilo; Araya Maturana, Ramiro; Gamboa, Consuelo (AMER CHEMICAL SOC, 1997-12-24)Deuterium quadrupole splittings from the aromatic ring of a series of linear benzyl-d(5) alkyl ethers, with alkyl chain length from 1 to 15 carbon atoms, have been measured using H-2-NMR spectroscopy. These molecules, 20% ...
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Ahumada, H.; Montecinos, R.; Alegría, S.; Araya Maturana, Ramiro; Weiss López, Boris (SOCIEDAD CHILENA DE QUIMICA, 2005-03)Molecular recognition based on chirality has fundamental importance in many biological processes. Deuterium quadrupole splittings from the aromatic ring and mesophase components of two series of optical isomers, L-and ...
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Fuentes, Eduardo; Araya Maturana, Ramiro; Méndez, Diego; Urra Faúndez, Félix; Mansilla, Santiago; Trostchansky, Andrés (Elsevier, 2020)
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Araya Maturana, Ramiro; Cardona, Wilson; Delgado Castro, Tomás; Jullian Matthaei, Carolina (JOHN WILEY & SONS LTD, 2000-02)The H-1 and C-13 NMR spectra of a set of structurally related tricyclic quinones consisting of 4,4-dimethylanthracene-1,9,10(4H)-trione (1), 4,4,6,7-tetramethylanthracene-1,9,10(4H)-trione (2) and the regioisomers 4,4,5- ...
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Araya Maturana, Ramiro; Cassels Niven, Bruce; Delgado Castro, Tomás; Hurtado Guzmán, Claudio; Jullian Matthaei, Carolina (JOHN WILEY & SONS LTD, 1999-04)The regiosomeric quinones 5-acetyloxymethyl-4,4,8-trimethyl- (5) and 8-acetyloxymethyl-4,4,5-trimethylanthracene-1,9,10(4H)-trione (6) were synthesized and their regiochemistry was assigned on the basis of the unambiguous ...
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Ruiz Fernández, A. R.; López Cascales, J. J.; Giner Casares, J. J.; Araya Maturana, Ramiro; Díaz Banose, F. G.; Weiss López, Boris (2016)Lyotropic nematic liquid crystals (lnlc) have attracted attention due to their resemblance to natural membranes and several technological applications. The effect of tetradecyltrimethyl ammonium chloride (TTAC) in the ...
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Weiss López, Boris; Jullian Matthaei, Carolina; Saitz Barría, Claudio; Pessoa Mahana, Hernán; Valderrama, J.; Araya Maturana, Ramiro (SOCIEDAD CHILENA DE QUIMICA, 2001-09)Activation parameters for the rotation around the methylene-nitrogen single bond found in a series of four 2,2'-disubstituted N-acetyl-N-phenylbenzylamines, dissolved in DMSO-d(6), were measured employing the temperature ...
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Martínez Cifuentes, Maximiliano; Salazar, Ricardo; Escobar, Carlos A.; Weiss López, Boris; Santos, Leonardo S.; Araya Maturana, Ramiro (Royal Soc Chemistry, 2015)In this work we present a study on the molecular structure and electrochemical behavior of a series of methoxylated 2'-hydroxychalcones, whose antitumor activity has been previously described. Cyclic voltammetry was used ...