Browsing by Author "8da1ba19-a5ff-4881-8476-343f0eb5a0e9"
Now showing items 1-20 of 42
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(American Chemical Society, 2015)We report the crystal face indexing and molecular spatial orientation, magnetic properties, electron paramagnetic resonance (EPR) spectra, and density functional theory (DFT) calculations of two previously reported oxovanadium ...
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(2012)The structure of the title compound, poly[(dihydrogenphosphato-?O)(mu 3-hydrogenphosphato)di-mu-oxido-(1,10-phenanthroline)copper(II)vanadium(V)], [CuV(HPO4)(H2PO4)O2(C12H8N2)]n, is defined by [(phen)Cu mu-(?2O:O'-VP2O10 ...
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(Royal Society of Chemistry, 2016)The synthesis and structure of a novel heteronuclear Cu-II and La-III metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported. The obtained MOF with the formula {[Cu0.5La2(HPDC)(PDC)(2)(SO4) ...
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(2004)DFT calculations on Cu4(μ3-X)4L 4 (X = H, CH3, CCH, F, Cl, Br, I; L = NH3, PH3) indicate that, regardless of its nature, X- acts essentially as a two-electron σ-type ligand and that the covalent part of the Cu⋯Cu bonding ...
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(American Chemical Society, 2015)© 2015 American Chemical Society.Rhenium complexes are versatile molecular building blocks whose tunable photophysical properties are useful in diverse opto-related applications. Herein we report the synthesis and ...
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(2004)The crystal structure of copper compound, [Cu2(VO 2)(HPO4)2 (NO3)(bpy)2].X was studied. These chemically isostructural systems were obtained by hydrothermal methods, which differ in the solvate molecules stabilizing the ...
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(Royal Soc. Chemistry, 2020)A family of hexaazamacrocyclic lanthanide complexes, [Ln(L-n)(NCS)(3)] (Ln(III) = Dy, Er; n = 1-3) has been synthesized and characterized by single-crystal X-ray diffraction, magnetic measurements and ab initio calculations. ...
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(Royal Society of Chemistry, 2014)In the present work, the synthesis and structural characterization of four new polyoxovanadoborate (BVO) frameworks based on the [V12B 18O60H6]10- polyanion are reported: (NH4)8(1,3-diapH2)[V12B 18O60H6]·5H2O (1), K ...
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(2009)A structural and magnetic characterization of a trinuclear chiral Mn(ll) formate three-dimensional framework exhibiting a triangular arrangement is presented. Compound Na3[Mn3(HCOO)9] was obtained by solvothermal synthesis ...
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(Amer Soc. Clinical Oncology, 2016)
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(Royal Society of Chemistry, 2016)A dinuclear cobalt(II), [Co2(kappa(4)-O,O', N,N'-L)(2)(mu-O,O'-HCOO)](ClO4)center dot(C2H5)(2)O (1) and a linear mixed valence trinuclear manganese, [Mn-3(kappa(4)-O,O', N,N'-L)(2)(mu-CH3O)(2)(mu-O,O'-CH3COO)(2)]center dot ...
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(American Chemical Society, 2015)© 2015 American Chemical Society. The spectroscopic, electrochemical, and photophysical properties of the new complex [P,N-{(C<inf>6</inf>H<inf>5</inf>)<inf>2</inf>(C<inf>5</i ...
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(American Chemical Society, 2020)To study how second-sphere interactions affect single-molecule magnet (SMM) properties of mononuclear lanthanide systems, two dysprosium(III) complexes [Dy(N-NCS)(3)(H2O)(5)]center dot 0.45(KSCN)(18-crown-6) (1) and ...
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(2013)A new 2-[(bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol copper(II) perchlorate, complex, [Cu-2(mu-SL)(2)](ClO4)(2) (1), was synthesized and magnetically and structurally characterized. The complex consists ...
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(American Chemical Society, 2019)The direct reaction of a series of substituted (1H-pyrazol-1-yl)pyridazine (L I : 6-(1H-pyrazolyl)pyridazine; L II : 3-chloro-6-(1H-pyrazole-1-yl)-pyridazine; L III : 6-(1H-3,5-dimethylpyrazolyl)pyridazine-3-carboxylic ...
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(American Chemical Society, 2020)A series of luminescent phenoxo-bridged dinuclear Tb-III complexes with tripodal ligands, 2,2'4 [(2-pyridinylmethyl)-imino]di(methylene)]-bis(4-R-phenol), where R = CH3 (L-CH3) (I), Cl (L-Cl) (II), CH3O (L-CH3O) (III), ...
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(2011)Structural, magnetic, and powder and single-crystal electron paramagnetic resonance (EPR) studies were performed on [{Cu(bipy)(en)}{Cu(bipy)(H2O)}{VO3}(4)](n) (bipy = 2,2'-bipyridine, en = ethylenediamine), which is a new ...
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(2008)A series of five compounds containing the bicyclo-[3.3.0]octa-2,6-diene skeleton are described, namely tetra-methyl cis,cis-3,7-dihydroxy-bicyclo-[3.3. 0]octa-2,6-diene-2,4-exo,6,8-exo-tetracarboxyl-ate, C16H18O10, (I), ...
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(2002)In acetonitrile, the cis-[MoO2]2+ group present in the anionic complex [MoO2(o-SC6H4COO)2]2-, can be functionalized under mild conditions by reaction with arylhydrazines, p-R-C6H4NHNH2. The resulting ionic complexes have ...
