Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)center dot H2O](n) and [Ba(Hoda)(2)](n) (H(2)oda : oxydiacetic acid)
Author | dc.contributor.author | Baggio, Ricardo | |
Author | dc.contributor.author | Garland, María Teresa | es_CL |
Author | dc.contributor.author | Leyva, Gabriela | es_CL |
Author | dc.contributor.author | Perec, Mireille | es_CL |
Author | dc.contributor.author | Polla, Griselda | es_CL |
Admission date | dc.date.accessioned | 2007-04-18T13:42:55Z | |
Available date | dc.date.available | 2007-04-18T13:42:55Z | |
Publication date | dc.date.issued | 2004-05-10 | |
Cita de ítem | dc.identifier.citation | INORGANICA CHIMICA ACTA 357 (7): 2185-2190 MAY 10 2004 | en |
Identifier | dc.identifier.issn | 0020-1693 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/124503 | |
Abstract | dc.description.abstract | The reaction of barium carbonate or hydroxide with oxydiacetic acid leads to the self-assembly of two barium oxydiacetate polymers in good yield: [Ba(oda) (.) H2O](n) (1) and [Ba(Hoda)(2)](n) (2). The products have been characterized by elemental analysis, IR, TGA and single crystal X-rav diffraction studies. The central barium atom in each mononuclear fragment is nine-coordinate in I and 10-coordinate in 2. These fragments are bridged by carboxylato groups in anti-anti conformation and through H-bonding interactions forming complex 3D networks. | en |
Lenguage | dc.language.iso | en | en |
Publisher | dc.publisher | ELSEVIER | en |
Keywords | dc.subject | X-RAY | en |
Título | dc.title | Synthesis and structure of two polymeric barium-oxydiacetates: [Ba(oda)center dot H2O](n) and [Ba(Hoda)(2)](n) (H(2)oda : oxydiacetic acid) | en |
Document type | dc.type | Artículo de revista |
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