| Author | dc.contributor.author | Calero, Rolando | |
| Author | dc.contributor.author | Manzur Saffie, Jorge | es_CL |
| Author | dc.contributor.author | Garland, María Teresa | es_CL |
| Author | dc.contributor.author | Baggio, Ricardo | es_CL |
| Admission date | dc.date.accessioned | 2007-04-18T15:00:51Z | |
| Available date | dc.date.available | 2007-04-18T15:00:51Z | |
| Publication date | dc.date.issued | 2004-03-20 | |
| Cita de ítem | dc.identifier.citation | JOURNAL OF COORDINATION CHEMISTRY 57 (5): 435-443 MAR 20 2004 | en |
| Identifier | dc.identifier.issn | 0095-8972 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/124507 | |
| Abstract | dc.description.abstract | The crystal and molecular structure of a copper complex formulated as Cu(bpma)(2)(.)[BF4](2), (bpma: N-{[3-(dimethoxymethyl)phenyl]methylidene}[di-(2-pyridyl)]methanamine) is reported. The ligand results from the reaction of the unmodified carboxaldehyde group of 1,3-benzene-dicarboxaldehyde with the solvent, methanol, giving the acetal. The structure is monomeric and contains the copper cation at a center of symmetry, octahedrally coordinated to two tridentate, symmetry-related bpma ligands. The charge balance is achieved through the inclusion in the structure of (highly disordered) BF4- counter ions. | en |
| Lenguage | dc.language.iso | en | en |
| Publisher | dc.publisher | TAYLOR & FRANCIS LTD | en |
| Keywords | dc.subject | 3-COORDINATE COPPER(I) COMPLEX | en |
| Título | dc.title | Structural characterization of Cu(bpma)(2)center dot[BF4](2), (bpma : N-{[3-(dimethoxyniethyl)phenyl]imethylidene}[di-(2-pyridyl)]methanamine) | en |
| Document type | dc.type | Artículo de revista | |
