Photochemical C-Cl bond activation of trichloroarenes by the rhenium complex (eta(5)-C5Me5)Re(CO)(3). X-ray structure of trans-(eta(5)-C5Me5)Re(CO)(2)(2-methoxy-4,5-dichlorophenyl)chloride
Author | dc.contributor.author | Aballay, Alvaro | |
Author | dc.contributor.author | Godoy, Fernando | es_CL |
Author | dc.contributor.author | Buono-Core, Gonzalo E. | es_CL |
Author | dc.contributor.author | Klahn, A. Hugo | es_CL |
Author | dc.contributor.author | Oelckers, Beatriz | es_CL |
Author | dc.contributor.author | Garland, María Teresa | es_CL |
Author | dc.contributor.author | Muñoz, Juan Carlos | es_CL |
Admission date | dc.date.accessioned | 2007-05-24T15:22:10Z | |
Available date | dc.date.available | 2007-05-24T15:22:10Z | |
Publication date | dc.date.issued | 2003-12-15 | |
Cita de ítem | dc.identifier.citation | JOURNAL OF ORGANOMETALLIC CHEMISTRY 688 (1-2): 168-173 DEC 15 2003 | en |
Identifier | dc.identifier.issn | 0022-328X | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/124634 | |
Abstract | dc.description.abstract | Photochemical reaction of (eta(5)-C5Me5)Re(CO)(3), with 2,4,5-trichloroanisole and 3,4,5-trichlorotrifluoromethylbenzene yields (eta(5)- C5Me5)Re(CO)(2)(C6H2Cl2(MeO))Cl (1) and (eta(5)-C5Me5)Re(CO)(2)(C6H2Cl2(CF3))Cl, (2) formed by insertion of the fragment (eta(5)- C5Me5)Re(CO)(2) into the C-Cl bond of the chloroarenes. The C-Cl bond activation of trichloroanisole occurs at the chlorine ortho respect to the methoxy group as revealed by the X-ray structure of 1. In the case of the reaction with C6H2Cl3(CF3), H-1-NMR spectroscopy indicates that only the C-Cl bond meta respect to CF3 group is cleaved. Complex 1 was isolated as the trans isomer while 2 was obtained as an isomeric mixture (trans-2 and cis-2). The stereochemistry of these complexes has been assigned by IR and C-13-NMR spectroscopies and supported by X-ray crystallography for 1. | en |
Lenguage | dc.language.iso | en | en |
Publisher | dc.publisher | ELSEVIER SCIENCE | en |
Keywords | dc.subject | CIS-TRANS ISOMERISM | en |
Título | dc.title | Photochemical C-Cl bond activation of trichloroarenes by the rhenium complex (eta(5)-C5Me5)Re(CO)(3). X-ray structure of trans-(eta(5)-C5Me5)Re(CO)(2)(2-methoxy-4,5-dichlorophenyl)chloride | en |
Document type | dc.type | Artículo de revista |
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