Structural effects in the kinetic behavior of the monomer-dimer surface reaction over nondeterministic fractal surfaces

Author	dc.contributor.author	Cortés, Joaquín
Author	dc.contributor.author	Valencia Astorga, Eliana	es_CL
Admission date	dc.date.accessioned	2007-06-01T19:23:48Z
Available date	dc.date.available	2007-06-01T19:23:48Z
Publication date	dc.date.issued	2003-11-15
Cita de ítem	dc.identifier.citation	JOURNAL OF COLLOID AND INTERFACE SCIENCE 267 (2): 391-396 NOV 15 2003	en
Identifier	dc.identifier.issn	0021-9797
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/124642
Abstract	dc.description.abstract	A study is made of the segregation effect of adsorbed species related to the inner structure of two bidimensional adsorbent fractals, the incipient percolation cluster (IPC) and the backbone of the IPC, and their connection with the rate-determining step of the kinetic mechanism of the monomer-dimer (MD) surface reaction on those fractals. Production, R-AB, is proportional to the concentration of A in the gas phase gamma(A) and to the fraction of vacant superficial sites x(E) (R-AB = gamma(A)x(E)), and it is shown that adsorption of the monomer is the rate-controlling step of the reaction mechanism.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	ACADEMIC PRESS INC ELSEVIER SCIENCE	en
Keywords	dc.subject	MONTE-CARLO-SIMULATION	en
Título	dc.title	Structural effects in the kinetic behavior of the monomer-dimer surface reaction over nondeterministic fractal surfaces	en
Document type	dc.type	Artículo de revista