Cyclopalladated complexes derivates of phenylhydrazones and their use as catalysts in ethylene polymerization

Author	dc.contributor.author	Pérez, Mónica A.
Author	dc.contributor.author	Quijada Abarca, Juan	es_CL
Author	dc.contributor.author	Ortega Jiménez, Orlando	es_CL
Author	dc.contributor.author	Álvarez Toledano, Cecilio	es_CL
Admission date	dc.date.accessioned	2007-06-07T14:28:04Z
Available date	dc.date.available	2007-06-07T14:28:04Z
Publication date	dc.date.issued	2005-02-15
Cita de ítem	dc.identifier.citation	JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL	en
Identifier	dc.identifier.issn	1381-1169
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/124656
Abstract	dc.description.abstract	New cyclopalladated complexes (Pd-A, Pd-B, Pd-C) were used as catalysts in ethylene polymerization. All of them show good activity, especially at a temperature of 80 degreesC. The molecular weight and molecular weight distribution obtained correspond to single-site catalysts, producing polymers with narrow molecular weight distribution. The melting points correspond to linear polyethylene. UV-visible spectroscopy studies were used to determine possible polymerization mechanisms.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	ELSEVIER SCIENCE BV	en
Keywords	dc.subject	METALLOCENE CATALYSTS	en
Título	dc.title	Cyclopalladated complexes derivates of phenylhydrazones and their use as catalysts in ethylene polymerization	en
Document type	dc.type	Artículo de revista