Gadolinium(III) and europium(III) L-glutamates: Synthesis and characterization
Author | dc.contributor.author | Barja, Beatriz | |
Author | dc.contributor.author | Baggio, Ricardo | es_CL |
Author | dc.contributor.author | Calvo, Rafael | es_CL |
Author | dc.contributor.author | Garland, María Teresa | es_CL |
Author | dc.contributor.author | Perec, Mireille | es_CL |
Author | dc.contributor.author | Rizzi, Alberto | es_CL |
Admission date | dc.date.accessioned | 2008-12-10T09:36:00Z | |
Available date | dc.date.available | 2008-12-10T09:36:00Z | |
Publication date | dc.date.issued | 2006-09-01 | |
Cita de ítem | dc.identifier.citation | INORGANICA CHIMICA ACTA Volume: 359 Issue: 12 Pages: 3921-3926 Published: SEP 1 2006 | en |
Identifier | dc.identifier.issn | 0020-1693 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/124753 | |
Abstract | dc.description.abstract | Two lanthanide(III) complexes with L-glutamate ligands [{Ln(2)(L-Glu)(2)(H2O)(8)}center dot 4(ClO4)center dot 2.5H(2)O](n) (Ln = Gd (1), Eu (2)) have been prepared and characterized by single-crystal X-ray diffraction. The compounds are isomorphous with infinite cationic 2D layers stacked together by secondary bonds. The building blocks are slightly different non-centrosymmetric dinuclear units placed in alternating layers, the resulting structures thus containing four non-equivalent Ln metal sites. The dinuclear units contain a fourfold bridge, two in the eta(1):eta(1):mu(2) and two in the eta(2):eta(1):mu(2) modes, from two alpha- and two gamma-carboxylates of four different L-Glu residues, respectively. | en |
Lenguage | dc.language.iso | en | en |
Publisher | dc.publisher | ELSEVIER | en |
Keywords | dc.subject | CAMBRIDGE STRUCTURAL DATABASE | en |
Título | dc.title | Gadolinium(III) and europium(III) L-glutamates: Synthesis and characterization | en |
Document type | dc.type | Artículo de revista |
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