| Author | dc.contributor.author | Cortés, Joaquín | |
| Author | dc.contributor.author | Valencia Astorga, Eliana | es_CL |
| Admission date | dc.date.accessioned | 2010-01-14T18:46:26Z | |
| Available date | dc.date.available | 2010-01-14T18:46:26Z | |
| Publication date | dc.date.issued | 2008-09-22 | |
| Cita de ítem | dc.identifier.citation | CHEMICAL PHYSICS LETTERS Volume: 463 Issue: 1-3 Pages: 251-257 Published: SEP 22 2008 | en_US |
| Identifier | dc.identifier.issn | 0009-2614 | |
| Identifier | dc.identifier.other | 10.1016/j.cplett.2008.08.033 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/125127 | |
| Abstract | dc.description.abstract | The reduction reaction of NO by CO over Pd is studied by means of a Monte Carlo simulation. A reaction mechanism similar to that established previously in the literature for Rh and a set of recently published kinetics parameters for Pd determined from experimental work are assumed. The heterogeneous effects of the catalytic substrate are analyzed by simulating various surfaces: a uniform square and hexagonal lattice, the incipient percolation cluster (IPC) fractal, and a lattice formed by a cluster distribution supported on a deterministic fractal. The results interpret reasonably the experimental data published recently in the case of crystals and supported catalysts. | en_US |
| Patrocinador | dc.description.sponsorship | The authors acknowledge the financial support of this work by
FONDECYT under Project No. 1070351. | en_US |
| Lenguage | dc.language.iso | en | en_US |
| Publisher | dc.publisher | ELSEVIER | en_US |
| Keywords | dc.subject | KINETIC PHASE-TRANSITIONS | en_US |
| Título | dc.title | Monte Carlo study of the influence of the structural heterogeneity of the surface in the CO-NO reaction on Pd and its relation with experimental data | en_US |
| Document type | dc.type | Artículo de revista | |
