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Authordc.contributor.authorLarrea, Edurne S. 
Authordc.contributor.authorFernández de Luis, Roberto 
Authordc.contributor.authorOrive, Joseba 
Authordc.contributor.authorIglesias, Marta 
Authordc.contributor.authorArriortua, María I. 
Admission datedc.date.accessioned2016-05-09T20:17:01Z
Available datedc.date.available2016-05-09T20:17:01Z
Publication datedc.date.issued2015
Cita de ítemdc.identifier.citationEur. J. Inorg. Chem. 2015, 4699–4707en_US
Identifierdc.identifier.otherDOI: 10.1002/ejic.201500431
Identifierdc.identifier.urihttps://repositorio.uchile.cl/handle/2250/138225
General notedc.descriptionArtículo de publicación ISIen_US
Abstractdc.description.abstractThe synthesis of a new mixed metal-organic framework ( M ' MOF) has been accomplished by the metalloligand approach. [ NaCu( 2,4- HPdc)( 2,4- Pdc)] ( 2,4- H2Pdc = pyridine2,4- dicarboxylic acid) has been obtained from the hydrothermal reaction of the metalloligand [ Cu( 2,4- HPdc) 2( H2O) 2] NaOH, and a transition metal salt. [ NaCu( 2,4- HPdc)( 2,4- Pdc)] is isostructural to [ CuMn( 2,4- Pdc) 2] and crystallizes in the triclinic space group P1. The 3D structure is built up from [ Cu( 2,4- HPdc) 2( H2O) 2] metalloligands and NaO6] octahedra in a pcu alpha- Po- like uninodal six- connected net. The compound is stable to 290 degrees C, and its crystal structure undergoes a 3% volume expansion between room temperature and thermal decomposition. The unsaturated CuII centers at the surface act as a heterogeneous Lewis acid catalyst for the cyanosilylation of aldehydes and Knoevenagel C- C bond- forming reactions. The catalytic activity has been compared with those of other copper( II) porous metalorganic frameworks such as HKUST- 1 and MOF- 74.en_US
Patrocinadordc.description.sponsorshipMinisterio de Economia y Competitividad (MEC) MAT2013-42092-R MAT2011-29020-C02-02 Gobierno Vasco (Basque University Research System Group) IT-630-13 University of the Basque Country (UPV/EHU) UFI 11/15en_US
Lenguagedc.language.isoenen_US
Publisherdc.publisherWileyen_US
Type of licensedc.rightsAtribución-NoComercial-SinDerivadas 3.0 Chile*
Link to Licensedc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/*
Keywordsdc.subjectHeterogeneous catalysisen_US
Keywordsdc.subjectMetal-organic frameworksen_US
Keywordsdc.subjectLigand designen_US
Keywordsdc.subjectCopperen_US
Keywordsdc.subjectUnsaturated metal centersen_US
Títulodc.title[NaCu(2,4-HPdc)(2,4-Pdc)] Mixed Metal-Organic Framework as a Heterogeneous Catalysten_US
Document typedc.typeArtículo de revista


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Atribución-NoComercial-SinDerivadas 3.0 Chile
Except where otherwise noted, this item's license is described as Atribución-NoComercial-SinDerivadas 3.0 Chile