Facultad de Ciencias Químicas y Farmacéuticas: Recent submissions
Now showing items 1161-1180 of 4850
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(2000)A novel cucurbitacin glycoside has been isolated from aerial parts of Kageneckia oblonga R. et P. and shown to be 3 beta-(beta-D-glucosyloxy)-16 alpha,23 alpha-epoxycucurbita-5,24-dien-11-one. The structure was established ...
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(1997)This paper reports a comprehensive study by cyclic voltammetry on the electrochemical characteristics and the reactivity of the one-electron reduction product from a series of nitro aryl 1,4-dihydropyridines in mixed and ...
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(Elsevier S.A., 2003)The title compound corresponds to a molecular product of the hydrothermal reaction of CuCl2, Zn, and BIPY (BIPY=2,2′-bipyridine) in the presence of phosphoric acid. The structure of the neutral complex Cu 4(μ2-Cl)4(BIPY)2 ...
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(Elsevier S.A., 2002)Reaction of propiolic acid (HCCCOOH) with dicobalt octacarbonyl (Co 2(CO)8) and tetracobalt dodecacarbonyl (Co 4(CO)12) leads to the organometallic carboxylic acids (CO)6Co2HCC-COOH (1) and (CO)10Co 4HCC-COOH (2) in good ...
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(2003)The electrochemical behavior of two representative 2,3-dihydro-7H-dibenzo[de,h]quinolin-7-ones was determined using cyclic voltammetry in DMSO as solvent and rationalized by quantum chemical calculations using ab initio ...
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(1973)The unimolecular decarboxylation of 6-nitrobenzisoxazole-3-carboxylate ion is strongly catalyzed by micelles of cationic and nonionic surfactants. The catalysis by cationic micelles can be enhanced by adding some electrolytes ...
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(National Institute on Alcohol Abuse and Alcoholism (NIAAA), 2002)The proteome is the complete set of proteins in an organism. It is considerably larger and more complex than the genome - the collection of genes that encodes these proteins. Proteomics deals with the qualitative and ...
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(2001)A hallmark event in transmissible spongiform encephalopathies is the conversion of the physiological prion protein into the disease-associated isoform. A natural polymorphism at codon 129 of the human prion gene, resulting ...
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(2003)The influence of a nonionic surfactant compound (sorbitan monooleate) on the coupled transport of Cu(II) ions in a hollow fiber-type solid supported liquid membrane extractor was studied. The acid compound 5-nonylsalicylaldoxime ...
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(2001)Melatonin and Vitamin B6 can be oxidized at the glassy carbon electrode showing well-resolved anodic peaks by differential pulse voltammetry. Vitamin B6 shows an oxidation peak potential of about 650 mV vs Ag/AgCI in ammonia ...
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(1969)The reactions between hydroxide or fluoride ion and p-nitrophenyl diphenyl phosphate, catalyzed by micelles of cetyltrimethylammonium bromide, are inhibited by phenyl, diphenyl, and p-t-butylphenyl phosphate. With decreasing ...
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(1987)The deactivation of a number of excited polycyclic aromatic hydrocarbons by copper(II), cobalt(II), nickle(II) and chromium(III) in ethanol-water (1:1 by volume) has been investigated. In spite of the fact that most of the ...
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Oxidation and catalytic properties of a binuclear copper(I) complex with a meta-xylyl spacer ligand (2003)The oxidation product of the binuclear copper (I) complex Cu2L(CIO4)2 (L = N,N′-bis-(6-methyl-2-pyridil) (2′-pyridyl)methyl m-xylylidene imine) has been isolated and structurally characterised. In the cupric species, ...
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(1998)The 1H and 13C NMR spectra of 2-phenyl-3H-naphtho[2,1-b][1,4]oxazin-3-one, 2-p-methoxyphenylnaphtho[1,2-d]oxazole and 2-phenylnaphtho[1,2-d]oxazole were totally assigned using a combination of one-and two-dimensional NMR ...
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(2003)Measurements of the electrical equivalent conductivity of potassium salts of poly(maleic acid-co-1-olefins), PA-nK(2) with n = 12, 18 has been carried out in methanol-water mixtures in the whole range of composition. The ...
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(2000)Electronic substituent effects may be rationalized in terms of Hammett- like linear relationships between global energy-dependent quantities and local electronic descriptors of reactivity. These linear relationships are ...
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(Elsevier, 2001)Detection of O2(1Δg) phosphorescence emission, λmax=1270nm, following laser excitation and steady state methods were employed to determine both the total constant, kT LID, and the chemical reaction rate constants, kR LID, ...
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(Elsevier Ltd, 2003)Copper(II) complexes with salen Schiff-base ligands derived from ethylenediamine or (S,S)-1,2-diphenylethylenediamine and salicylaldehyde or 5-methoxy, 5-bromo and 5-nitrosalicylaldehyde have been tested as catalysts for ...
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(Archivos Latinoamericanos Nutricion, 2000)A study for the characterization of frozen giant squid mantle (meat) protein stored at -25°C for 8 month was started. In the present research, the folowing functional properties were investigate: emulsifying, water holding ...
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(2002)A reliable methodology for identification and quantification of Polycyclic Aromatic Hydrocarbons (PAHs) in atmospheric aerosols has been developed, using extraction with dichloromethane, a clean-up step for purification ...