Now showing items 1899-1918 of 2801

    • Ushak, S.; Spodine Spiridonova, Evgenia; Venegas Yazigi, Diego; Le Fur, Eric; Pivan, J. Y. (ELSEVIER, 2006-09-08)
      The hybrid organic/inorganic copper oxovanadium diphosphonates of formula [Cu(bipy)(VO2)(2)(O3PCH2PO3)H2O] 1, which crystallizes in the orthorhombic symmetry, and [Cu(bipy)(VO2)(O3P(CH2)(2)PO2OH)] (.) 1.5H(2)O 2, which ...
    • Jeria, Yanara; Bazaes, Aliosha; Báez, María E.; Espinoza, Jeannette; Martínez, Jessica I.; Fuentes, Edwar (Elsevier B.V., 2017)
      © 2016 Elsevier B.V.This paper presents a method for the determination of imidacloprid in honeybees based on the measurement of excitation-emission spectra of photo-induced fluorescence (PIF-EEMs) associated to unfolded ...
    • Silva, Salom; Olea, Andrés F.; Thomas, J. K. (1991)
      Photoexcitation of 1‐pyrenyldiazomethane (1) leads to carbenes which attach to various molecules, e.g. surfactants, polymers, hydroxylated surfaces. This provides a convenient method of labelling these compounds with pyrene ...
    • Encina, M. V.; Lissi Gervaso, Eduardo A.; Olea, F. A. (1980)
      The photochemistry of alkanals in dilute solutions and in the presence of olefins and hydrogen donors was analysed and the results obtained are discussed taking as reference the photochemical behaviour of the alkanones. ...
    • Scaiano, J. C.; Encinas, M. V.; Lissi Gervaso, Eduardo A.; Zanocco Loyola, Antonio; Das, P. K. (1986)
      The photochemistry of alkyl pyruvates of the type CH3COCOOCHR2 has been examined in solution using a combination of product studies and laser flash photolysis techniques. The results indicate that the main reaction path ...
    • Zanocco Loyola, Antonio; Soto, E. A.; Lissi Gervaso, Eduardo A.; Scaiano, J. C. (1990)
      The photochemistry of ethyl esters of α-oxo-carboxylic acids of the type RCOCO2CH2CH3 was examined using a combination of steady state irradiation and laser flash photolysis techniques. The experimental results indicate ...
    • Acosta, Alison; Antipán, Javier; Fernández, Mariano; Prado, Gaspar; Sandoval Altamirano, Catalina Paz; Gunther Sapunar, Germán; Gutiérrez Urrutia, Izabook; Poblete Castro, Ignacio; Vega, Andrés; Pizarro, Nancy (Royal Soc Chemistry, England, 2021)
      In this work, we describe the photoisomerization of facial rhenium(I) tricarbonyl complexes bearing P,Nbidentate pyridyl/phosphine ligands with different chelating rings and anions: RePNBr, RePNTfO, and RePNNBr, which ...
    • Sanhueza, Luis; Castro, Joaquín; Urzúa, Esteban; Barrientos, Lorena; Oyarzún Ampuero, Felipe; Pesenti, Héctor; Shibue, Toshimichi; Sugimura, Natsuhiko; Tomita, Wataru; Nishide, Hiroyuki; Moreno Villoslada, Ignacio (American Chemical Society, 2015)
      Photochromic solid materials based on the cationic polymer poly(decylviologen) are reported. The solids were obtained by freeze-drying colloidal suspensions of nanocomplexes obtained by mixing aqueous solutions of the ...
    • Encinas, M. Victoria; Lissi Gervaso, Eduardo A.; Vásquez, M.; Olea, Andrés F.; SILVA, E. (1989)
      Abstract The quenching of the benzophenone triplet by lysozyme and its constituent amino acids in aqueous solutions have been studied. Native lysozyme quenches the benzophenone triplet with a high rate constant, 4 × ...
    • Pizarro Urzúa, Nancy A.; Günther Sapunar, Germán; Núñez Vergara, Luis (ELSEVIER SCIENCE, 2007-06-10)
      A different photophysical and photochemical behavior has been found between two second generation antihypertensive 1,4-dihydropyitidines (1,4-DHPs), felodipine and nimodipine. While nimodipine was observed as being more ...
    • Sandoval Altamirano, Catalina; Fuente, J. R. de la; Berríos, Eduardo; Sánchez, S. A.; Pizarro, N.; Morales, J.; Gunther, Georgia (Elsevier Science SA, 2018)
      Phenalenone has been extensively studied due to its photophysical behavior. However, fewer are the articles referring to the phenalenone derivatives as singlet oxygen generators. The incorporation of substituents on the ...
    • Nonell, Santi; Ferreras, Lourdes R.; Cañete, Alvaro; Lemp Miranda, Else; Günther Sapunar, Germán; Pizarro, Nancy; Zanocco Loyola, Antonio (AMER CHEMICAL SOC, 2008-07-18)
      The photophysics and photochemistry of a series of naphthoxazinones have been studied using a combination of methods ranging from steady-state and time-resolved spectroscopic techniques to product analysis. The photophysics ...
    • Fuente, J. de la; Cañete Molina, Alvaro Félix; Saitz Barría, Claudio; Jullian Matthaei, Carolina (AMER CHEMICAL SOC, 2002-08-08)
      Photoreduction of 3-phenylquinoxalin-2-ones, XNQ, by triethylamine, TEA, gives a metastable semireduced quinoxalin-2-one via an electron-proton-electron transfer, with unit quantum yields at high amine concentrations. ...
    • Norambuena V., Ester; Olea Azar, Claudio; Rufs, A. M.; Encinas, M. V. (ROYAL SOC CHEMISTRY, 2004-03-21)
      The reduction of several nitrobenzenes bearing electron-donor and electron-withdrawing substituents in the 4-position by triethylamine in acetonitrile was studied by cyclic voltammetry, EPR spectroscopy, and steady-state ...
    • Fuente, Julio R. de la; Aliaga, Christian; Cañete, Alvaro; Kciuk, Gabriel; Szreder, Tomasz; Bobrowski, Krzysztof (The American Society of Photobiology, 2013)
      Photoreduction of 7H-benzo[e]perimidin-7-one (3-AOIA, A1) and its 2-methyl derivative (2-Me-3-AOIA, A2) by non-Hdonating amines (1,4-diazabicyclo[2.2.2]octane [DABCO]; 2,2,6,6-tetramethylpiperidine [TMP]), and a ...
    • Fuente, J. de la; Neira Pacheco, Verónica Alejandra; Saitz Barría, Claudio; Jullian Matthaei, Carolina; Sobarzo Sánchez, Eduardo (AMER CHEMICAL SOC, 2005-07-07)
      Photoreduction by amines of oxoisoaporphine dyes occurs via a stepwise mechanism of electron-proton electron transfer that leads to the metastable N-hydrogen oxoisoaporphine anion. During photoreduction that occurs from ...
    • De la Fuente, Julio; Aliaga, Christian; Poblete, Cristian; Zapata, Gerald; Jullian Matthaei, Carolina; Saitz Barría, Claudio; Cañete, Alvaro; Kciuk, Gabriel; Sobarzo Sánchez, Eduardo; Bobrowski, Krzysztof (2009)
      Photoreduction of oxoisoaporphine (OIA) (l-aza-benzo-[de]anthracen-7-one) and its 5-methoxy (5-MeOOIA) derivative by selected amines (two non-a-hydrogen-donating amines (l,4-diaza[2.2.2]-bicyclooctane (DABCO) and ...
    • Fuente, J. de la; Jullian Matthaei, Carolina; Saitz Barría, Claudio; Sobarzo Sánchez, Eduardo; Neira Pacheco, Verónica Alejandra; González, C.; López, R.; Pessoa Mahana, Hernán (ROYAL SOC CHEMISTRY, 2004)
      Photoreduction of 5,6-dimethoxy-, 5-methoxy- and 2,3-dihydro-7H-dibenzo[de, h] quinolin-7-one (A) by tertiary amines in oxygen-free solutions generates long-lived semi-reduced metastable photoproducts, A - NH-, via a ...
    • Lemp Miranda, Else; Cañete, Alvaro; Günther Sapunar, Germán; Pizarro, Nancy; Zanocco Loyola, Antonio (ELSEVIER, 2008-09-25)
      The photophysical properties, the capacity to produce singlet molecular oxygen by sensitization and the photostability of a series of 20 aryloxazinones and one quinoxalinone have been evaluated using a combination of methods ...
    • Almada, M.; Leal Martínez, B. H.; Hassan, N.; Kogan Bocian, Marcelo; Burboa, M. G.; Topete, A.; Valdez, M. A.; Juarez, J. (Elsevier, 2017)
      Gold nanorods (GNR) use has been proposed in medical applications because of their intrinsic photothermal properties. However, the presence of CTAB molecules adsorbed onto the surface of GNRs results in a highly cytotoxic ...