Browsing by Author "Squella Serrano, Juan"
Now showing items 21-40 of 177
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Bollo Dragnic, Soledad; Yáñez Soto, Claudia; Sturm Schaub, Juan; Núñez Vergara, Luis; Squella Serrano, Juan (AMER CHEMICAL SOC, 2003-04-15)Potassium ferricyanide ([Fe(CN)(6)](3-)) reduction and ferrocenemethanol (Fe-OH) oxidation at a beta-cyclodextrin (beta-CD)-modified gold electrode were investigated by cyclic voltammetry (CV) and scanning electrochemical ...
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Bollo Dragnic, Soledad; Yáñez, Claudia; Sturm, Juan; Núñez Vergara, Luis; Squella Serrano, Juan (2003)Potassium ferricyanide (Fe(CN)6]3-) reduction and ferrocenemethanol (Fc-OH) oxidation at a β-cyclodextrin (β-CD)-modified gold electrode were investigated by cyclic voltammetry (CV) and scanning electrochemical microscopy ...
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Ortíz Yáñez, María Eugenia; Núñez Vergara, Luis; Squella Serrano, Juan (ELSEVIER SCIENCE, 2002-02-08)We have studied the O-2/O-2(.-) redox couple on the HMDE in DMSO aprotic media, obtaining optimal conditions of both oxygen concentration and scan rate in order to avoid oscillatory phenomena. By choosing the oxygen ...
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Ortiz,; Núñez Vergara, Luis; Squella Serrano, Juan (2002)We have studied the O2/O2·- redox couple on the HMDE in DMSO aprotic media, obtaining optimal conditions of both oxygen concentration and scan rate in order to avoid oscillatory phenomena. By choosing the oxygen concentration ...
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Bollo Dragnic, Soledad; Núñez Vergara, Luis; Squella Serrano, Juan (ELSEVIER SCIENCE, 2004-01-15)PA-824 (2-nitro-6-(4-trifluoromethoxy-benzyloxy)-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine) is being tested as antituberculosis drug. Little is known on the action mechanism of PA-824; however the reduction of the nitro ...
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Bollo Dragnic, Soledad; Núñez Vergara, Luis; Bontá, M.; Chauviere, G.; Perie, J.; Squella Serrano, Juan (ELSEVIER SCIENCE, 2001-09-21)Megazol (2-amino-5-(1-methyl-5-nitro-2-imdazolyl)-1,3,4-thiadiazol, CAS 19622-55-0) and related nitroimidazole compounds are being tested as antichagasic drugs. Little is known on the mode of action of megazol. However, ...
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Carbajo, J.; Bollo Dragnic, Soledad; Núñez Vergara, Luis; Campero, A.; Squella Serrano, Juan (ELSEVIER SCIENCE, 2002-08-23)We have chosen 4-nitroimidazole (4-NIm) as a prototype of nitroimidazolic compounds in order to carry out an exhaustive cyclic voltammetric study in protic media, 0.1 M Britton-Robinson buffer+0.3 M KCl with ethanol as a ...
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Cyclic voltammetry and digital simulation of the electroreducction of ortho-and meta-nitro aryl ... Bollo Dragnic, Soledad; Núñez Vergara, Luis; Squella Serrano, Juan (Sociedad Chilena de Química, 1999)Cyclic voltammetry (CV) and digital simulation methods are utilezed to elucidate the mechanism of electrochemical reduction of a series of nitro aryl 1,4-dihydropyridines im protic (aqueous) and mixed media. The experimental ...
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Cyclic voltammetry and digital simulation of the electroreduction of ortho- and meta-nitro aryl ... Bollo Dragnic, Soledad; Núñez Vergara, Luis; Squella Serrano, Juan (1999)Cyclic voltammetry (CV) and digital simulation methods are utilized to elucidate the mechanism of electrochemical reduction of a series of nitro aryl 1,4-dihydropyridines in protic (aqueous) and mixed media. The experimental ...
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Bollo Dragnic, Soledad; Finger Caraccioli, Sebastián; Sturm Schaub, Juan; Núñez Vergara, Luis; Squella Serrano, Juan (PERGAMON-ELSEVIER, 2007-04-20)The heterogeneous electron transfer reaction for the reduction of some nitroso aromatic derivatives in aqueous-alcoholic medium was studied on both mercury and glassy carbon electrodes (GCE) by using cyclic voltammetry ...
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Merino, M.; Núñez Vergara, Luis; Squella Serrano, Juan (SOCIEDAD CHILENA DE QUIMICA, 2000-09)Carbon paste electrodes were modified with cytochrome c reductase enzyme. The behavior of the electrodes was characterized by cyclic voltammetry. The cytochrome c reduction was investigated both on the enzyme modified ...
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Gamboa, J.; Cornejo, L.; Acarapi, J.; Squella Serrano, Juan (Sociedad Chilena de Quimica, 2013)As (III) was determined by differential pulse polarography (DPP) in 1 mol L-1 HCl as supporting electrolyte. For quantification, the -0.35 V peak (versus Ag/AgCl) was chosen. The obtained detection and quantification limits ...
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Mozo, J. D.; Carbajo, J.; Sturm Schaub, Juan; Núñez Vergara, Luis; Salgado, P.; Squella Serrano, Juan (Wiley, 2012)A new, sensitive, reproducible and easy-to-use flow-injection method for determining nifuroxazide based on adsorptive stripping linear sweep voltammetry over screen-printed carbon electrodes is presented. The presented ...
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Yáñez Soto, Claudia; Núñez Vergara, Luis; Squella Serrano, Juan (WILEY-V C H VERLAG GMBH, 2002-04)Carbon paste electrodes modified with beta-cyclodextrin have been investigated for voltammetric determination of nitrendipine. The immobilization of the beta-cyclodextrin on the carbon paste leads to a modification of the ...
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Yáñez,; Núñez Vergara, Luis; Squella Serrano, Juan (2002)Carbon paste electrodes modified with β-cyclodextrin have been investigated for voltammetric determination of nitrendipine. The immobilization of the β-cyclodextrin on the carbon paste leads to a modification of the electrode ...
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Yáñez, C.; Núñez Vergara, Luis; Squella Serrano, Juan (2003)The formation of inclusion complexes of well-known 1,4-dihydropyridine calcium antagonists, such as nifedipine (NF) and nicardipine (NC), with beta-cyclodextrin (betaCD) was investigated by differential pulse polarography ...
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Álvarez Lueje, Alejandro; Pujol, Silvina; Núñez Vergara, Luis; Squella Serrano, Juan (AOAC INTERNATIONAL, 2002-11)Lercanidipine in ethanol-0.04M Britton-Robinson buffer (20 + 80) gives an irreversible anodic response on a glassy carbon electrode in a broad pH range (2-12) that depends on pH. This signal can be attributed to oxidation ...
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Núñez Vergara, Luis; Pardo Jiménez, V; Barrientos, C.; Olea Azar, Claudio; Navarrete-Encina, P. A.; Squella Serrano, Juan (2012)In this study, two series of dihydropyridine-fused and pyridine-fused coumarins were synthesised and electrochemically characterised in aprotic medium. In both series, the most easily reducible groups were the endocyclic ...
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Maya Arango, Juan; Morello Casté, Antonio; Repetto Scaramelli, Yolanda; Tellez Neubauer, Rowena; Rodríguez, A.; Zelada, U.; Puebla, P.; Caballero S., Esther; Medarde, M.; Núñez Vergara, Luis; Squella Serrano, Juan; Bontá, M.; Bollo Dragnic, Soledad; Feliciano M., Arturo San (PERGAMON-ELSEVIER SCIENCE, 2000-01)A series of 3-chloro-phenyl-1,4-dihydropyridine derivatives produced different degrees of inhibition of parasite growth and respiration on clone Brener, LQ and Tulahuen strains of Trypanosome cruzi epimastigotes. Respiratory ...
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Moscoso Cabello, Raúl Andrés; Inostroza Briones, Elías; Bollo Dragnic, Soledad; Squella Serrano, Juan (Springer, 2016)We report that glassy carbon electrode (GCE) modified with multiwalled carbon nanotubes (MWCNTs) can encapsulate or entrap 3,5-dinitrobenzoic acid (35DNB) generating a 35DNB-MWCNTGC electrode. After electrochemical reduction ...