Browsing by Subject "Chemistry (all)"
Now showing items 21-40 of 59
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(1969)The reactions between hydroxide or fluoride ion and p-nitrophenyl diphenyl phosphate, catalyzed by micelles of cetyltrimethylammonium bromide, are inhibited by phenyl, diphenyl, and p-t-butylphenyl phosphate. With decreasing ...
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(1970)Micellar effects upon the reaction between hydroxide ion and bis-2,4-dinitrophenyl phosphate to give 2,4-dinitrophenyl phosphate have been examined. The reaction is catalyzed up to 30-fold by cationic micelles of ...
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(1996)The transport of copper from EI Teniente's mine waters by solvent extraction in a membrane extractor using a hollow fiber as solid support as solid support has been studied. LIX-860, a salicylaldoxime was used as carrier. ...
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(1985)We report results of Xα valence bond scattered wave (Xα-VB-SW) calculations for a variety of clusters that mimic the active sites in iron-sulfur proteins: Fe(SR)41-,2- (R = H, CH3), Fe2S2(SH)42-,3-, and Fe4S4(SCH3)42-,3-. ...
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(Royal Society of Chemistry, 2010)A novel iridium complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand was synthesized and its optical properties studied. The presence of Zn2+ ions specifically perturbs the excited state, giving rise to ...
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(Sociedad Chilena de Quimica, 2014)© 2014, Sociedad Chilena de Quimica. All rights reserved. We report a voltammetric study of several nitroaromatic compounds such as the drugs: Nifedipine, Nitrendipine, Furnidipine and Nisoldipine in multiwalled carbon ...
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(2005)Two new homologous series of chiral esters derived from Schiff's bases containing a 1,3,4-thiadiazole unit (series 6 and 7) were synthesized and their liquid crystalline and ferroelectric properties investigated. All the ...
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(Royal Society of Chemistry, 2005)The new hybrid organic-inorganic copper oxovanadium phosphates of composition Cu4(bipy)4V4O11(PO 4)2·nH2O (n ∼ 5) (1) and Cu 2(bipy)2V2P2O12 (2) (bipy = 2, 2′-bipyridine) adopting the triclinic symmetry were obtained by ...
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(2005)A novel molecular tetrameric zinc cluster with phosphate bridges has been synthesized by a hydrothermal method and characterized by X-ray diffraction. The structure is stabilized by neutral H 3PO 4 and water molecules. ...
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(2004)The synthesis and phase characterization of three homologous series of liquid crystalline acrylic and methacrylic monomers, consisting of 21 new compounds are presented. They are based on ω-hexyloxy- and ω-undecyloxysali ...
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Phase characterization of two homologous series of LC methacrylic monomers based on ω-hexyl- and ... (2003)The phase characterization of two homologous series of liquid crystalline methacrylic monomers based on ω-hexyl- and ω-butyloxysalicylaldimine groups, with different alkoxy tails, is presented. The liquid crystalline ...
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(1990)The photochemistry of ethyl esters of α-oxo-carboxylic acids of the type RCOCO2CH2CH3 was examined using a combination of steady state irradiation and laser flash photolysis techniques. The experimental results indicate ...
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(1996)(2'E, 6'E, 10'E, 14'E)-2-(8',9'-dione-3', 7', 11', 15'-tetramethylhexadeca-2', 6', 10', 14'-tetraenyl)-6-Methyl-1,4-benzoquinone, (2'E, 6'E, 10'E, 14'E)-2-(8'-one, 15'-formyl-3', 7', 11', trimethylhexadeca-2', 6', 10', ...
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(2006)The synthesis, characterization and electrochemistry of a novel nanocomposite based on the co-intercalation of lithium and poly(acrylonitrile) (PAN) in molybdenum disulfide [Li0.6MoS2(PAN) 1.2·0.5H2O] is described. The ...
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(2003)Detection of singlet molecular oxygen, O2(1Δ g), by phosphorescence emission, λ = 1270 nm, following laser excitation was employed to measure the quantum yield of O2( 1δg) generation by the antimalaric drugs quinine, ...
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(1988)The kinetics of the quenching of excited pyrene by several molecules in a variety of hydrocarbon solvents and in a diol are reported. The rate constants for reaction of the excited pyrene are, for the most part, ...
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(1996)The azomethin ylide of the 2-p-methoxyphenyl-4-phenyl-2-oxazolin-5-one underwent 1,3-dipolar cycloaddition to both tautomers of the 1-nitroso-2-naphthol. The reaction yields two naphthoxazoles: 2-phenylnaphtho[1,2-d]oxazole, ...
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(1996)The reactivity of the electrochemically generated nitro radical anion from nicardipine, nitrendipine and nimodipine, all nitro aryl 1,4-dihydropyridine derivative, with relevant thiols, was quantitatively assessed by cyclic ...
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(2012)Photoisomerization of a protein bound chromophore is the basis of the light sensing and signaling responses of many photoreceptors. Z-to-E photoisomerization of the Pr Cph1Δ2 phytochrome has been investigated by polarization ...