Browsing by Subject "Catalysis"
Now showing items 1-20 of 23
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(Royal Society of Chemistry, 2014)The metal-organic framework [Cu2(bipy)2(btec)] ∞ was used as a heterogeneous catalyst in the liquid phase oxidation of styrene and cyclohexene with tert-butylhydroperoxide (TBHP) as the oxidant either in water-dichloroethane ...
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(Royal Society of Chemistry, 2019)The synthesis and characterization of a new ruthenium(ii) complex containing a hemilabile P^N-ligand are reported. The catalytic activity of this complex was evaluated in the hydrogen transfer reaction of acetophenone and ...
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(Royal Society of Chemistry, 2017)The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. ...
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(1973)The unimolecular decarboxylation of 6-nitrobenzisoxazole-3-carboxylate ion is strongly catalyzed by micelles of cationic and nonionic surfactants. The catalysis by cationic micelles can be enhanced by adding some electrolytes ...
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(2000)Electronic substituent effects may be rationalized in terms of Hammett- like linear relationships between global energy-dependent quantities and local electronic descriptors of reactivity. These linear relationships are ...
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(Royal Society of Chemistry, 2017)© The Royal Society of Chemistry 2017.{[Cu3Ln2(oda)6(H2O)6]•nH2O}n (LnIII: La, Gd, Yb; odaH2: oxydiacetic acid) are reported as reusable heterogeneous catalysts in the oxidation of olefins. An influence of the LnIII ion ...
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(Royal Society of Chemistry, 2015)© The Royal Society of Chemistry 2015.Carbon monoxide hydrogenation was studied over a γ-alumina-supported 1 wt% Rh catalyst by means of kinetic and in situ infrared measurements. The study was carried out at 200-300 °C, ...
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(1960)Two crystalline forms of bis-(5-aminotetrazolato)-copper (II) have been prepared and characterized. Visible and ultraviolet spectra of aqueous copper (II)-5-aminotetrazole solution have been examined. Continuous variation ...
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(1969)The reactions between hydroxide or fluoride ion and p-nitrophenyl diphenyl phosphate, catalyzed by micelles of cetyltrimethylammonium bromide, are inhibited by phenyl, diphenyl, and p-t-butylphenyl phosphate. With decreasing ...
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(1970)Micellar effects upon the reaction between hydroxide ion and bis-2,4-dinitrophenyl phosphate to give 2,4-dinitrophenyl phosphate have been examined. The reaction is catalyzed up to 30-fold by cationic micelles of ...
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(1985)We report results of Xα valence bond scattered wave (Xα-VB-SW) calculations for a variety of clusters that mimic the active sites in iron-sulfur proteins: Fe(SR)41-,2- (R = H, CH3), Fe2S2(SH)42-,3-, and Fe4S4(SCH3)42-,3-. ...
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(Royal Society of Chemistry, 2010)A novel iridium complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand was synthesized and its optical properties studied. The presence of Zn2+ ions specifically perturbs the excited state, giving rise to ...
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Oxidation and catalytic properties of a binuclear copper(I) complex with a meta-xylyl spacer ligand (2003)The oxidation product of the binuclear copper (I) complex Cu2L(CIO4)2 (L = N,N′-bis-(6-methyl-2-pyridil) (2′-pyridyl)methyl m-xylylidene imine) has been isolated and structurally characterised. In the cupric species, ...
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(Elsevier Ltd, 1997)Copper(II) complexes of the ligands (6-methyl-2,2′-dipyridyl)methane (MeDPM) and (6,6′-dimethyl-2,2′-dipyridyl)methane (diMeDPM) were prepared and used as catalysts for the oxidation of 3,5-ditert-butylcatechol to ...
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(1988)The kinetics of the quenching of excited pyrene by several molecules in a variety of hydrocarbon solvents and in a diol are reported. The rate constants for reaction of the excited pyrene are, for the most part, ...
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(2012)Photoisomerization of a protein bound chromophore is the basis of the light sensing and signaling responses of many photoreceptors. Z-to-E photoisomerization of the Pr Cph1Δ2 phytochrome has been investigated by polarization ...
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(SOCIEDAD CHILENA DE QUIMICA, 2005-12)The catalysis of the hydroesterification and hydroformylation-acetalization of 1-hexene by rhodium(I), cis-[Rh(CO)2(amine)2](PF6) complexes (amine = pyridine, 2-picoline, 3-picoline, 4-picoline, 3,5-lutidine or 2,6-lutidine) ...
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(American Chemical Society, 2001)Continuum solvent effect on the electrophilicity index recently proposed by Parr and co-workers (Parr, R. G.; von Szentpaly, L.; Liu, S. J. Am. Chem. Soc. 1999, 121, 1922) is discussed in detail. Solvent effect is introduced ...
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(Royal Society of Chemistry, 2016)The [(phen)((HO)-O-2)Re(CO)(3)](+)(CF3SO3)(-) salt, 1(+)(CF3SO3-), has been crystallized in the form of two new solvates, [(phen)(H2O)Re(CO)(3)](+)(CF3SO3)(-)center dot(C4H8O)(0.5) and [(phen)(H2O)Re(CO)(3)](+)(CF3SO3)(-)center ...
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(1983)The photochemistry of several phenyl alkyl and p-anisyl alkyl ketones has been examined using laser flash photolysis and conventional quantum yield techniques. The methoxy-substituted ketones show higher activation energies ...
