Browsing by Subject "Inorganic Chemistry"
Now showing items 1-13 of 13
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(2004)DFT calculations on Cu4(μ3-X)4L 4 (X = H, CH3, CCH, F, Cl, Br, I; L = NH3, PH3) indicate that, regardless of its nature, X- acts essentially as a two-electron σ-type ligand and that the covalent part of the Cu⋯Cu bonding ...
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(Royal Society of Chemistry, 2014)In the present work, the synthesis and structural characterization of four new polyoxovanadoborate (BVO) frameworks based on the [V12B 18O60H6]10- polyanion are reported: (NH4)8(1,3-diapH2)[V12B 18O60H6]·5H2O (1), K ...
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(2009)A structural and magnetic characterization of a trinuclear chiral Mn(ll) formate three-dimensional framework exhibiting a triangular arrangement is presented. Compound Na3[Mn3(HCOO)9] was obtained by solvothermal synthesis ...
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(Royal Society of Chemistry, 2009)A new extended metal-organic framework [Cu(H(2)btec)(bipy)](infinity) (1) (H(4)btec=1,2,4,5-benzenetetracarboxylic acid; bipy= 2,2'-bipyridine) has been hydrothermally synthesized. Violet crystals are formed in a monoclinic ...
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(Royal Society of Chemistry, 2018)© 2018 The Royal Society of Chemistry. Heterometallic 3d-4f inorganic polymers were prepared using 3,5 pyridinedicarboxylic acid (H2PDC), {[CuLn2(PDC)2(SO4)2(H2O)6]·H2O}n (Ln: SmIII, CuSmPDC, EuIII, CuEuPDC, GdIII, and ...
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(2007)The methoxycarbonylation of alkenes catalyzed by palladium(ii) complexes with P,N-donor ligands, 2-(diphenylphosphinoamino)pyridine (Ph 2PNHpy), 2-[(diphenylphosphino)methyl]pyridine (Ph 2PCH2py), and 2-(diphenylphosphin ...
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(Royal Society of Chemistry, 2019)In the search for a more effective chemotherapy for the treatment of Chagas' disease and human African trypanosomiasis, caused by Trypanosoma cruzi and Trypanosoma brucei parasites, respectively, the use of organometallic ...
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Preparation of new cationic complexes [(η5-C5H5)Fe(dppe)L]PF6 with sulphur and other donor ligands (1994)The reaction of (η5-C5H5)Fe(dppe)I with the ligand L′ (L′ = S2(CH3)2, C6H5SNR2 (R = CH3, C6H11), S(NC4H8O)2, P(n-Bu)3, tetrahydrofuran and NC5H5 in the presence of T1PF6 have been investigated. Formation of the new cationic ...
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(2010)When excess uronic acid over CrVI is used, the oxidation of d-glucuronic acid (Glucur) by CrVI yields D-glucaric acid (Glucar) and CrIII as final products. The redox reaction involves the formation of intermediate CrIV and ...
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(2011)The physiologically occurring copper-glutathione complex, [Cu(I)-[GSH]2], has the ability to react continually with oxygen, generating superoxide anions (O 2 -). We addressed here the effects that superoxide removal has ...
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(2006)Full title: Two new hybrid organic/inorganic copper(II)-oxovanadate(V) diphosphonates: [Cu2(phen)2(O3PCH2PO 3)(V2O5)(H2O)]·H 2O and [Cu2(phen)2(O3P(CH 2)3PO3)(V2O5)] ·C3H8. Synthesis, structure, and magnetic properties. ...
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(1981)The IR and Raman spectra of solid diamminemercury(II) chloride with 14N/15N and H/D isotopic substitution have been measured. The spectra have been interpreted assuming D3d symmetry for the [Hg(NH3)2]2+ cations which have ...