Nucleophilicity scale for n- and pi-nucleophiles

Author	dc.contributor.author	Jaramillo, Paula
Author	dc.contributor.author	Fuentealba Rosas, Patricio	es_CL
Author	dc.contributor.author	Pérez López, Patricia	es_CL
Admission date	dc.date.accessioned	2009-04-09T17:41:58Z
Available date	dc.date.available	2009-04-09T17:41:58Z
Publication date	dc.date.issued	2006-08-31
Cita de ítem	dc.identifier.citation	CHEMICAL PHYSICS LETTERS Volume: 427 Issue: 4-6 Pages: 421-425 Published: AUG 31 2006	en
Identifier	dc.identifier.issn	0009-2614
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/118812
Abstract	dc.description.abstract	A recently introduced empirical nucleophilicity index for a series of n- and pi-nucleophiles was evaluated. The index is based on the frontier molecular orbital information of the nucleophile and its electrophilic partner. The model is validated against kinetic data of alkenes, phosphanes, phosphites and amines interacting with the corresponding electrophilic partner. The predictive character of this index is tested for some nucleophiles.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	ELSEVIER	en
Keywords	dc.subject	DIELS-ALDER REACTIONS	en
Título	dc.title	Nucleophilicity scale for n- and pi-nucleophiles	en
Document type	dc.type	Artículo de revista