| Author | dc.contributor.author | Contreras Ramos, Renato | |
| Author | dc.contributor.author | Gómez Jeria, Juan | es_CL |
| Admission date | dc.date.accessioned | 2011-10-26T18:59:14Z | |
| Available date | dc.date.available | 2011-10-26T18:59:14Z | |
| Publication date | dc.date.issued | 1986 | |
| Cita de ítem | dc.identifier.citation | Acta sud Americana de Química, VoI.6, 1986 | es_CL |
| Identifier | dc.identifier.issn | 0716 - 0402 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119341 | |
| Abstract | dc.description.abstract | Self Consistent Reaction Field (SCRF) ealculations, including
dielectric solvent effects, have been performed to analyze the
relative stabilities of the different chernical species found in substitution
reactions involving benzilic substrates. The results obtained
using the SCRF model, implemented within the SCF - CNDO/2 approach,
show that the major part of the solvent stabilization manifests
itself during dissociation rather than the formation of ion pairs
structures present as intermediate states. | es_CL |
| Patrocinador | dc.description.sponsorship | This work has received financial support from the University of Chile (D1B Projects
Q2001 and Q1759) and from Fondo Nacional de Ciencia (Projects 5031 and 1075). | es_CL |
| Lenguage | dc.language.iso | en | es_CL |
| Publisher | dc.publisher | Editorial Codelia | es_CL |
| Título | dc.title | Ion pairs as intermediates in substitutions of benzilic substrates. A scrf study including solvent effects | es_CL |
| Document type | dc.type | Artículo de revista | |
