Two polymorphic forms of a mixed zinc/copper biquinoline dihydrogenphosphate
| Author | dc.contributor.author | Moreno, Yanko | es_CL |
| Author | dc.contributor.author | Hermosilla, Patricio | es_CL |
| Author | dc.contributor.author | Garland, María Teresa | es_CL |
| Author | dc.contributor.author | Peña, Octavio | es_CL |
| Author | dc.contributor.author | Baggio, Ricardo | es_CL |
| Admission date | dc.date.accessioned | 2008-05-14T14:07:59Z | |
| Available date | dc.date.available | 2008-05-14T14:07:59Z | |
| Publication date | dc.date.issued | 2007 | es_CL |
| Cita de ítem | dc.identifier.citation | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS Vol. 63 JUN 2007 Part 6 M249-M252 | es_CL |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/120434 | |
| General note | dc.description | Publicación ISI | es_CL |
| Abstract | dc.description.abstract | Two polymorphic forms of a mixed zinc/copper biquinoline dihydrogenphosphate are presented, showing almost identical monomeric units, viz. (2,2 '-biquinoline-kappa N-2,N ')bis(dihydrogenphosphato-kappa O)copper(II)/zinc(II), formulated as [ZnxCu1-x(H2PO4)(2)(C18H12N2)], with x = 0.88 (1) and 0.90 (2). The cation is tetrahedrally coordinated to a chelating biquinoline system and two diprotonated phosphate anions. The structures differ mainly in their intermolecular hydrogen-bonding interactions, leading to different packing schemes. No significant evidence of stress due to the Zn/Cu solid solution formation was detected. | es_CL |
| Lenguage | dc.language.iso | en | es_CL |
| Keywords | dc.subject | CRYSTAL-STRUCTURE | es_CL |
| Area Temática | dc.subject.other | Crystallography | es_CL |
| Título | dc.title | Two polymorphic forms of a mixed zinc/copper biquinoline dihydrogenphosphate | es_CL |
| Document type | dc.type | Artículo de revista |
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