Redetermination of catena-poly[bis[chloro(mu-pyridine N-oxide-kappa O-2 : O)copper(II)]-di-mu-chloro]

Author	dc.contributor.author	Atria Salas, Ana María
Author	dc.contributor.author	Cortés, P.	es_CL
Author	dc.contributor.author	Garland, María Teresa	es_CL
Author	dc.contributor.author	Baggio, Ricardo	es_CL
Admission date	dc.date.accessioned	2009-09-04T16:10:14Z
Available date	dc.date.available	2009-09-04T16:10:14Z
Publication date	dc.date.issued	2003-11
Cita de ítem	dc.identifier.citation	ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 59: M967-M969 Part: 11	en
Identifier	dc.identifier.issn	1600-5368
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/120802
Abstract	dc.description.abstract	The title compound, [Cu2Cl4(C5H5NO)(2)](n), is a one-dimensional polymer in which the Cu-II atoms are alternately bridged by two O atoms [Cu...Cu = 3.2131 (10) Angstrom] and two Cl atoms [Cu...Cu = 3.7061 (11) Angstrom]. The metal centers display a very distorted coordination geometry, with the four stronger bonds defining a CuCl2O2 polyhedron midway between square planar and tetrahedral, which serves as the base of a pyramid, while the loosely bound Cl atom in the bridge occupies the apex. The simultaneous presence of a good hydrogen-bond acceptor and an adequate C - H donor leads to a network of C-H...Cl interactions.	en
Lenguage	dc.language.iso	en	en
Publisher	dc.publisher	BLACKWELL MUNKSGAARD	en
Keywords	dc.subject	CRYSTAL STRUCTURE	en
Título	dc.title	Redetermination of catena-poly[bis[chloro(mu-pyridine N-oxide-kappa O-2 : O)copper(II)]-di-mu-chloro]	en
Document type	dc.type	Artículo de revista