INTRAMOLECULAR [4+2] DIELS-ALDER CYCLOADDITIONS OF 2-SUBSTITUTED PHOSPHABENZENE AND ARSABENZENE IN TRIOSMIUM CLUSTERS

Author	dc.contributor.author	Arce, A. J.
Author	dc.contributor.author	Deeming, A. J.	es_CL
Author	dc.contributor.author	DeSanctis, Y.	es_CL
Author	dc.contributor.author	García, A. M.	es_CL
Author	dc.contributor.author	Manzur Saffie, Jorge	es_CL
Author	dc.contributor.author	Spodine Spiridonova, Evgenia	es_CL
Admission date	dc.date.accessioned	2010-09-21T20:02:50Z
Available date	dc.date.available	2010-09-21T20:02:50Z
Publication date	dc.date.issued	1994-09
Cita de ítem	dc.identifier.citation	ORGANOMETALLICS 13(9): 3381-3383	en_US
Identifier	dc.identifier.issn	0276-7333
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/121046
Abstract	dc.description.abstract	2-(Trimethylsilyl)-1-phosphabenzene and -1-arsabenzene, Me(3)SiC(5)H(4)E (E = P, AS), react with [Os3H2(CO)(10)] to give the clusters [Os3H2(Me(3)SiC(5)H(4)E)(CO)(9)], which contain sigma-bonded, four-electron-donating mu 3-heterocyclic ligands, and the products [Os3H{(Me(3)Si)(2)C(10)H(9)E(2)}(CO)(9)], having tricyclic mu(3)-ligands derived from [4 + 2] Diels-Alder cycloadditions.	en_US
Lenguage	dc.language.iso	en	en_US
Publisher	dc.publisher	Amer. Chem. Soc.	en_US
Keywords	dc.subject	COMPLEXES	en_US
Título	dc.title	INTRAMOLECULAR [4+2] DIELS-ALDER CYCLOADDITIONS OF 2-SUBSTITUTED PHOSPHABENZENE AND ARSABENZENE IN TRIOSMIUM CLUSTERS	en_US
Document type	dc.type	Artículo de revista