TRIAMMINE COBALT(III)-L-MALATE - MALATE ION AS A TRIDENTATE LIGAND

Author	dc.contributor.author	Bunel Torrealba, Sergio	es_CL
Author	dc.contributor.author	Ibarra, Carmen	es_CL
Author	dc.contributor.author	Calvo Pérez, Víctor	es_CL
Author	dc.contributor.author	Blasko, Andrei	es_CL
Author	dc.contributor.author	Bunton, Clifford A.
Author	dc.contributor.author	Keder, N. L.	es_CL
Admission date	dc.date.accessioned	2011-06-08T14:20:16Z
Available date	dc.date.available	2011-06-08T14:20:16Z
Publication date	dc.date.issued	1991
Cita de ítem	dc.identifier.citation	POLYHEDRON 10 (20-21): 2495-2500	es_CL
Identifier	dc.identifier.issn	0277-5387
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/121249
General note	dc.description	Artículo de publicación ISI	es_CL
Abstract	dc.description.abstract	The crystal structure of the title compound has been determined from single crystal X-ray diffraction data. There is little angle strain in the complex which has two carboxylate ions and one alkoxide ion bound to cobalt(III). These conclusions agree with IR, CD and NMR spectral data except that H-1 coupling constants show that the conformation of the malate ligand differs slightly in solid and solution. The three ammonia ligands have different H-1 chemical shifts and different rates of hydrogen exchange in D2O.	es_CL
Lenguage	dc.language.iso	en	es_CL
Publisher	dc.publisher	PERGAMON-ELSEVIER SCIENCE LTD	es_CL
Keywords	dc.subject	OPTICAL-ACTIVITY	es_CL
Título	dc.title	TRIAMMINE COBALT(III)-L-MALATE - MALATE ION AS A TRIDENTATE LIGAND	es_CL
Document type	dc.type	Artículo de revista