Chemiluminescent recombination of acetyl radicals

Author	dc.contributor.author	Fuente, J. de la
Author	dc.contributor.author	Lissi Gervaso, Eduardo A.	es_CL
Admission date	dc.date.accessioned	2011-07-27T19:25:00Z
Available date	dc.date.available	2011-07-27T19:25:00Z
Publication date	dc.date.issued	1986
Cita de ítem	dc.identifier.citation	Boletín de la Sociedad Chilena de Química 31 (3): 123-128	es_CL
Identifier	dc.identifier.issn	0366-1644
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/121502
Abstract	dc.description.abstract	Pyrolysis of di-terbutylperoxyoxalate at 45ºC in the presence of acetaldehyde produces quantitative yields of tertbutanol and biacetyl. Luminescence arising from excited biacetyl is produced during the peroxide decomposition. The excited mpolecules are produced in the recombination of two acetyl radicals: 2 CH3CO → 3CH3COCOCH3 (1) The yield of excited molecules in the recombination of two acetyl radicals is 1.3 x 10-4.	es_CL
Lenguage	dc.language.iso	en	es_CL
Publisher	dc.publisher	Sociedad Chilena de Química	es_CL
Keywords	dc.subject	Acetyl radicals	es_CL
Título	dc.title	Chemiluminescent recombination of acetyl radicals	es_CL
Document type	dc.type	Artículo de revista