Two Cd and Hg peroxodisulfate complexes with aromatic amines
Author | dc.contributor.author | Díaz de Vivar, Enriqueta | |
Author | dc.contributor.author | Harvey, Miguel Angel | es_CL |
Author | dc.contributor.author | Garland, María Teresa | es_CL |
Author | dc.contributor.author | Baggio, Sergio | es_CL |
Author | dc.contributor.author | Baggio, Ricardo | es_CL |
Admission date | dc.date.accessioned | 2007-04-18T20:14:48Z | |
Available date | dc.date.available | 2007-04-18T20:14:48Z | |
Publication date | dc.date.issued | 2005-05 | |
Cita de ítem | dc.identifier.citation | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 61: M240-M244 Part 5, MAY 2005 | en |
Identifier | dc.identifier.issn | 0108-2701 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/124523 | |
Abstract | dc.description.abstract | The crystal structures of two complexes containing the peroxodisulfate anion are reported, namely mu-peroxodisulfato-1 kappa O:2 kappa O'-bis[(acetato-kappa O-2,O')aqua(2,2':6',2 ''-terpyridine-kappa N-3,N',N '')cadmium(II)] heptahydrate, [Cd-2(C2H3O2)(2)(S2O8)(C15H11N2)(2)(H2O)(2)]center dot 7H(2)O, (I), and catena-poly[[[bis(2,2'-bi-pyridine-kappa N-2,N')mercury(II)]-mu-peroxodisulfato-kappa O-2:O'] 0.4-hydrate], {[Hg(C10H8N2)(2)(S2O8)]center dot 0.4H(2)O}(n), (II). In both structures, the anion behaves as a bridge, linking neighbouring coordination polyhedra in two different ways, either tightly bound to the heptacoordinated Cd2+ cation forming neatly separated dimeric entities in (I) or across a shorter O-S-O path producing weakly connected chains by way of 'semi-coordination' to the Hg2+ cations in (II). | en |
Lenguage | dc.language.iso | en | en |
Publisher | dc.publisher | BLACKWELL MUNKSGAARD | en |
Keywords | dc.subject | MOLECULAR-STRUCTURE | en |
Título | dc.title | Two Cd and Hg peroxodisulfate complexes with aromatic amines | en |
Document type | dc.type | Artículo de revista |
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