Quantitative characterization of the global philicity patterns of common diene/dienophile pairs in cycloaddition reactions II: the interacting pair model
| Author | dc.contributor.author | Pérez Méndez, Claudio | |
| Author | dc.contributor.author | Contreras Ramos, Renato | |
| Admission date | dc.date.accessioned | 2015-07-30T14:36:47Z | |
| Available date | dc.date.available | 2015-07-30T14:36:47Z | |
| Publication date | dc.date.issued | 2015 | |
| Cita de ítem | dc.identifier.citation | Tetrahedron Letters 56 (2015) 1767–1770 | en_US |
| Identifier | dc.identifier.other | doi: 10.1016/j.tetlet.2015.01.199 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/132240 | |
| General note | dc.description | Artículo de publicación ISI | en_US |
| Abstract | dc.description.abstract | We present a unified model of electrophilicity and nucleophilicity that considers the electrophile/nucleophile pair in an interacting regime, thereby avoiding the arbitrariness of defining them as the opposite ends of a unique reactivity scale. The model is validated against rate coefficients for the cycloaddition of azomethine ylides towards substituted acetylenes and Michael addition of a series of 1-(X-substituted phenyl)-2-propyn-1-ones towards hydrazine. | en_US |
| Patrocinador | dc.description.sponsorship | Fondo de Innovacion para la Competitividad del Ministerio de Economia, Fomento y Turismo, Chile ICM-P10-003-F CILIS Fondecyt 1110062 | |
| Lenguage | dc.language.iso | en | en_US |
| Publisher | dc.publisher | Elsevier | en_US |
| Type of license | dc.rights | Atribución-NoComercial-SinDerivadas 3.0 Chile | * |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | * |
| Keywords | dc.subject | Nucleophilicity | en_US |
| Keywords | dc.subject | Electrophilicity | en_US |
| Keywords | dc.subject | Cycloaddition | en_US |
| Keywords | dc.subject | Michael addition | en_US |
| Título | dc.title | Quantitative characterization of the global philicity patterns of common diene/dienophile pairs in cycloaddition reactions II: the interacting pair model | en_US |
| Document type | dc.type | Artículo de revista |
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Except where otherwise noted, this item's license is described as Atribución-NoComercial-SinDerivadas 3.0 Chile