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Author | dc.contributor.author | Chayet, Liliana | |
Author | dc.contributor.author | Rojas, Cecilia | |
Author | dc.contributor.author | Cardemil, Cecilia | |
Author | dc.contributor.author | Jabalquinto, Ana María | |
Author | dc.contributor.author | Vicuña, Ana María | |
Author | dc.contributor.author | Cori, Ana María | |
Admission date | dc.date.accessioned | 2018-12-20T14:08:10Z | |
Available date | dc.date.available | 2018-12-20T14:08:10Z | |
Publication date | dc.date.issued | 1977 | |
Cita de ítem | dc.identifier.citation | Archives of Biochemistry and Biophysics, Volumen 180, Issue 2, 2018, Pages 318-327 | |
Identifier | dc.identifier.issn | 10960384 | |
Identifier | dc.identifier.issn | 00039861 | |
Identifier | dc.identifier.other | 10.1016/0003-9861(77)90044-3 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/154123 | |
Abstract | dc.description.abstract | A soluble enzyme preparation from the flavedo of Citrus limonum transforms [1-3H1]neryl pyrophosphate or [1-3H1]geranyl pyrophosphate into β-pinene, sabinene, α-pinene, and limonene. The enzyme has been partially purified and stabilized by precipitation with polyethyleneglycol. The enzymic cyclization requires the presence of Mn2+, which cannot be replaced with Mg2+. The addition of reagents containing sulfhydryl groups is essential for optimal activity. Allylic C10 monophosphates do not act as substrates, but they inhibit hydrocarbon formation. Inorganic pyrophosphate has a similar inhibitory effect. No interconversion of neryl and geranyl pyrophosphate has been observed. Possible pathways for the enzymic cyclization reactions are proposed. © 1977. | |
Lenguage | dc.language.iso | en | |
Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
Source | dc.source | Archives of Biochemistry and Biophysics | |
Keywords | dc.subject | Biophysics | |
Keywords | dc.subject | Biochemistry | |
Keywords | dc.subject | Molecular Biology | |
Título | dc.title | Biosynthesis of monoterpene hydrocarbons from [1-3H]neryl pyrophosphate and [1-3H]geranyl pyrophosphate by soluble enzymes from Citrus limonum | |
Document type | dc.type | Artículo de revista | |
Cataloguer | uchile.catalogador | SCOPUS | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |
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