Iron(II) and manganese(I) complexes containing diphosphine ligands. An infrared study of BrMn(CO)2 (dppm)P(OPh)3 and CpFe(dppe)R (R = I, CN)
| Author | dc.contributor.author | Campos, M. M.V. | |
| Author | dc.contributor.author | Diaz, C. V. | |
| Author | dc.contributor.author | Figueroa, K. | |
| Author | dc.contributor.author | Padilla, L. C. | |
| Author | dc.contributor.author | Lara H., N. | |
| Author | dc.contributor.author | Diaz, G. F. | |
| Admission date | dc.date.accessioned | 2018-12-20T14:11:49Z | |
| Available date | dc.date.available | 2018-12-20T14:11:49Z | |
| Publication date | dc.date.issued | 1994 | |
| Cita de ítem | dc.identifier.citation | Vibrational Spectroscopy, Volumen 7, Issue 1, 2018, Pages 61-72 | |
| Identifier | dc.identifier.issn | 09242031 | |
| Identifier | dc.identifier.other | 10.1016/0924-2031(94)85041-0 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/154659 | |
| Abstract | dc.description.abstract | Infrared spectra in the region 4000-70 cm-1 are recorded for [1,2-bis(diphenylphosphino)methane](triphenylphosphite)bromo (cis,cis- and trans-dicarbonyl)manganese, and η5-cyclopentadienyl-[1,2-bis(diphenylphosphino)ethane]iron(cyano) and -iodo complexes. Particular emphasis is given to the assignment of the metal-ligand bands, for which a normal coordinate analysis based on a simplified molecular model is performed. Effect of the isomerization and ligand substitution on the structure, stability and reactivity of all the complexes is also discussed. © 1994. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Vibrational Spectroscopy | |
| Keywords | dc.subject | Band assignment | |
| Keywords | dc.subject | Diphosphine ligands | |
| Keywords | dc.subject | Infrared spectrometry | |
| Keywords | dc.subject | Iron(II) | |
| Keywords | dc.subject | Mn(I) | |
| Keywords | dc.subject | Normal coordinate analysis | |
| Keywords | dc.subject | Valence force field | |
| Título | dc.title | Iron(II) and manganese(I) complexes containing diphosphine ligands. An infrared study of BrMn(CO)2 (dppm)P(OPh)3 and CpFe(dppe)R (R = I, CN) | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
Files in this item
This item appears in the following Collection(s)
-
Artículos de revistas
Artículos de revistas
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile