Electrochemical behaviour of NN′-thiobisamines. Cyclic voltammetry in dimethyl sulphoxide with low water content
Author
dc.contributor.author
González Moraga, Guillermo
Author
dc.contributor.author
Santa Ana, María Angélica
Author
dc.contributor.author
Chadwick, Isabel
Admission date
dc.date.accessioned
2018-12-20T14:41:24Z
Available date
dc.date.available
2018-12-20T14:41:24Z
Publication date
dc.date.issued
1983
Identifier
dc.identifier.issn
1472779X
Identifier
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10.1039/P29830001803
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/157081
Abstract
dc.description.abstract
The electrochemical behaviour of NN′-thiobispiperidine and NN′-thiobismorpholine in dimethyl sulphoxide at low water content has been studied by cyclic voltammetry. Electro-oxidation in this medium, producing SO<inf>2</inf> at the electrode surface, parallels the process observed by adding a Brönsted acid in which acid catalysed hydrolysis generates an intermediate species which is followed by a disproportionation process.