Author | dc.contributor.author | Brubaker, Carl | |
Admission date | dc.date.accessioned | 2018-12-20T15:05:11Z | |
Available date | dc.date.available | 2018-12-20T15:05:11Z | |
Publication date | dc.date.issued | 1960 | |
Cita de ítem | dc.identifier.citation | Journal of the American Chemical Society, Volumen 82, Issue 1, 1960, Pages 82-85 | |
Identifier | dc.identifier.issn | 15205126 | |
Identifier | dc.identifier.issn | 00027863 | |
Identifier | dc.identifier.other | 10.1021/ja01486a017 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/157707 | |
Abstract | dc.description.abstract | Two crystalline forms of bis-(5-aminotetrazolato)-copper (II) have been prepared and characterized. Visible and ultraviolet spectra of aqueous copper (II)-5-aminotetrazole solution have been examined. Continuous variation experiments reveal 1:2 interactions and a formation constant for the complex in solution has been determined and is about 1012. Infrared studies suggest coördination involves the ring and not the 5-amino group. Acids decompose the complexes and bring about rupture of the tetrazole ring, while decomposition by ammonia does not affect the ring. | |
Lenguage | dc.language.iso | en | |
Source | dc.source | Journal of the American Chemical Society | |
Keywords | dc.subject | Catalysis | |
Keywords | dc.subject | Chemistry (all) | |
Keywords | dc.subject | Biochemistry | |
Keywords | dc.subject | Colloid and surface chemistry | |
Título | dc.title | Metal tetrazole complexes: bis-(5-aminotetrazolato)-copper (II) | |
Document type | dc.type | Artículo de revista | |
dcterms.accessRights | dcterms.accessRights | Acceso a solo metadatos | |
Cataloguer | uchile.catalogador | rvh | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |