Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands
| Author | dc.contributor.author | Moya, S. A. | |
| Author | dc.contributor.author | Vidal, M. | |
| Author | dc.contributor.author | Abarca, G. | |
| Author | dc.contributor.author | Martinez, C. | |
| Author | dc.contributor.author | Guerchais, V. | |
| Author | dc.contributor.author | Le Bozec, H. | |
| Author | dc.contributor.author | Garland, María Teresa | |
| Author | dc.contributor.author | Rodriguez, S. | |
| Author | dc.contributor.author | Aguirre, P. | |
| Admission date | dc.date.accessioned | 2018-12-20T15:10:29Z | |
| Available date | dc.date.available | 2018-12-20T15:10:29Z | |
| Publication date | dc.date.issued | 2010 | |
| Cita de ítem | dc.identifier.citation | Inorganic Chemistry Communications, Volumen 13, Issue 12, 2018, Pages 1519-1521 | |
| Identifier | dc.identifier.issn | 13877003 | |
| Identifier | dc.identifier.other | 10.1016/j.inoche.2010.09.001 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/158197 | |
| Abstract | dc.description.abstract | The synthesis and characterization of new ruthenium(II) carbonyl complexes containing polypyridine and triphenylphosphine ligands is reported. Crystallographic information obtained for the trans-PPh3-[Ru(biq) (PPh3)2(CO)]Cl2 complex (biq = 2,2'-biquinoline) reveals five-coordination on the metal. The complexes were studied as catalysts in hydrogen transfer reactions in basic solution. Turnover frequencies in the 2250-817 h-1 range were determined in 1 hour of reaction with a substrate/catalysts ratio of 830. © 2010 Elsevier B.V. All rights reserved. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Inorganic Chemistry Communications | |
| Keywords | dc.subject | Polypyridine ligands | |
| Keywords | dc.subject | Ruthenium carbonyl | |
| Keywords | dc.subject | Ruthenium complex | |
| Keywords | dc.subject | Transfer hydrogenation | |
| Título | dc.title | Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile