Structure and bonding in the hydrothermally synthesized copper(I) complex Cu4(μ2-Cl)4(BIPY)2
| Author | dc.contributor.author | Moreno, Yanko | |
| Author | dc.contributor.author | Spodine Spiridonova, Evgenia | |
| Author | dc.contributor.author | Vega, Andrés | |
| Author | dc.contributor.author | Saillard, Jean Yves | |
| Admission date | dc.date.accessioned | 2018-12-20T15:20:39Z | |
| Available date | dc.date.available | 2018-12-20T15:20:39Z | |
| Publication date | dc.date.issued | 2003 | |
| Cita de ítem | dc.identifier.citation | Inorganica Chimica Acta, Volumen 350, | |
| Identifier | dc.identifier.issn | 00201693 | |
| Identifier | dc.identifier.other | 10.1016/S0020-1693(02)01494-9 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/158853 | |
| Abstract | dc.description.abstract | The title compound corresponds to a molecular product of the hydrothermal reaction of CuCl2, Zn, and BIPY (BIPY=2,2′-bipyridine) in the presence of phosphoric acid. The structure of the neutral complex Cu 4(μ2-Cl)4(BIPY)2 determined by means of X-ray diffraction consists of molecular units constructed around a Cu4 parallelogram, with diagonally opposed tetrahedral and linear copper centers. DFT calculations provide a rationalization of the bonding in this molecule. © 2003 Elsevier Science B.V. All rights reserved. | |
| Lenguage | dc.language.iso | en | |
| Publisher | dc.publisher | Elsevier S.A. | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Inorganica Chimica Acta | |
| Keywords | dc.subject | Bonding | |
| Keywords | dc.subject | Copper(I) | |
| Keywords | dc.subject | DFT | |
| Título | dc.title | Structure and bonding in the hydrothermally synthesized copper(I) complex Cu4(μ2-Cl)4(BIPY)2 | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile