Browsing by Author "Parada Aliste, José"
Now showing items 1-15 of 15
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(Elsevier, 1998)The I3- salts soluble in acetone and sparingly so in methanol, and I3- inhibits formation of Co(II) so that minor decomposition of acomplex does not broaden its 1H NMR signals. The (phen)2 complex of Co(III) with D-glucosamine ...
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(Sociedad Chilena de Química, 1997)D-β-Mannosamine reacts with cobalt(III) bis-phenanthroline to form a single 1:1 complex with the ∆ configuration at Co(III) which can be isolated as the stable triiodide salt.
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(ELSEVIER SCI LTD, 2000-10-20)The Delta-[Co(III)bis(phenanthroline)(sucrose)](3+) complex forms with little perturbation of the sucrose conformation, and complexation by HO-2(g) and HO-1(f).
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(Sociedad Chilena de Quimica, 2010)D-Glucose derivatives 1,2:5,6-di-O-isopropyline-a-D-glucofuranose (1) and 1,2-O-isopropyline-a-D-glucofuranose (2) with Ti(IV) are chiral catalysts in the addition of diethylzinc to benzaldehyde. The Ti(IV)-carbohydrate ...
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(SOC BRASILEIRA QUIMICA, 2009)A derivative of D-xylose, 1,2-O-isopropylidene-alpha-D-xylofuranose (1), with Ti((OPr)-Pr-i)(4) was used as a chiral catalyst in the asymmetric alkylation of benzaldehyde with diethylzinc (Et2Zn) for the high-yield production ...
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(SOCIEDAD CHILENA DE QUIMICA, 2006-06)Mixed complexes of animosugars and 1,10-phenanthroline (phen) with cobalt(III), with the composition Co(III)(phen)(2)sugar, disproportionate in aqueous solution in approximately one month, giving non ionic tris-aminosugar ...
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(1999)The Δ-Λ isomerization of partially resolved [Ni(1,10-phen)2(S-aa)]+ systems, where S-aa is S-phenylalaninate, S-isoleucinate, S-leucinate, S-valinate, or S-alaninate, has been studied at 15,20 and 25°C in methanol as ...
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(John Wiley & Sons Ltd., 2014)Palladium(II) complexes containing phosphine donor ligands derived from naphthyl(diphenyl)phosphine were synthesized and characterized by NMR and elemental analysis. The complexes were studied as catalyst precursors in ...
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(2001)Mixed complexes of bis-phenanthroline cobalt(III) and α-D-galactose or β-D- or L-arabinose are identified in aqueous solution from their 1H NMR and circular dichroism (CD) spectra. Galactose forms only the Δ-complex, but ...
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(SOC CHILENA QUIMICA, 2008-09)This study describes the fast and simultaneous determination of glutathione and glutathione disulfide by Capillary Zone Electrophoresis in plant extracts of shoot and root of tomato plants. Frequent use of acidic precipitation ...
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(2002)Reaction between cis-[Co(NH3)(H2O)(2)](3-) and ammonia in aqueous solution, in the presence of a carbohydrate, leads to the formation of the tetranuclear complex of cobalt (III): [Co-4(NH3)(12)(OH)(6)](6+) partially resolved. ...
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(SOC CHILENA QUIMICA, 2008-03)A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to ...
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(PERGAMON-ELSEVIER SCIENCE LTD, 2005-06-28)The title compound (sucrose Co(phen)(2)) is a dication with the Delta-configuration at Co(III) and ligation through O-2(g) and OH-1(f). Earlier geometrical optimization with semi-empirical PM3(tm) parameters had fitted ...
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(PERGAMON-ELSEVIER SCIENCE LTD, 2002-10-01)The two 1,10-phenanthroline ligands in the mixed Delta-cobalt(III) complex with sucrose are in different environments relative to the sucrose ligand as shown by differences in their H-1 NMR signals and predicted by structural ...
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(2004)Complexes of the type Delta- and Lambda-[Co(diimine)(2)carbohydrate](2+) were synthesized with the diimines: 1,10-phenanthroline and 2,2'-bipyridine and with the carbohydrates: aminosugars, hexoses, pentoses and sucrose, ...
