Enantioselective diamination of alkenes by use of a bisimidoosmium reagent with the aid of chiral catalysts
| Author | dc.contributor.author | Almodovar, Iriux | |
| Author | dc.contributor.author | Hovelmann, Claas H. | es_CL |
| Author | dc.contributor.author | Streuff, Jan | es_CL |
| Author | dc.contributor.author | Martin Nieger, Martín | es_CL |
| Author | dc.contributor.author | Muñiz, Kilian | es_CL |
| Admission date | dc.date.accessioned | 2008-12-04T15:46:22Z | |
| Available date | dc.date.available | 2008-12-04T15:46:22Z | |
| Publication date | dc.date.issued | 2006-01-30 | |
| Cita de ítem | dc.identifier.citation | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY Issue: 3 Pages: 704-712 Published: JAN 30 2006 | en |
| Identifier | dc.identifier.issn | 1434-193X | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/120576 | |
| Abstract | dc.description.abstract | The development of a new method for the diamination of alkenes is reported. It is based on a reaction in the presence of stoichiometric or catalytic amounts of chiral auxiliaries, which permits the direct synthesis of enantiomerically enriched osmaimidazolidines. The combined application of a catalyst-directing oxazolidinone group and a titanium catalyst results in enantioselective alkene diamination with enantiomer ratios of up to 95:5. Absolute configurations of representative osmaimidazolidine products were established unambiguously by solid-state structure analyses. | en |
| Lenguage | dc.language.iso | en | en |
| Publisher | dc.publisher | WILEY-V C H VERLAG GMBH | en |
| Keywords | dc.subject | SHARPLESS ASYMMETRIC AMINOHYDROXYLATION | en |
| Título | dc.title | Enantioselective diamination of alkenes by use of a bisimidoosmium reagent with the aid of chiral catalysts | en |
| Document type | dc.type | Artículo de revista |
Files in this item
This item appears in the following Collection(s)
-
Artículos de revistas
Artículos de revistas