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Authordc.contributor.authorUzcátegui, G. C. 
Authordc.contributor.authorHung, F. es_CL
Authordc.contributor.authorOrtega, Marisol C. es_CL
Authordc.contributor.authorPardey, Alvaro J. es_CL
Authordc.contributor.authorLongo, C. es_CL
Authordc.contributor.authorAguirre, P. es_CL
Authordc.contributor.authorMoya, S. A. es_CL
Admission datedc.date.accessioned2009-05-20T10:27:40Z
Available datedc.date.available2009-05-20T10:27:40Z
Publication datedc.date.issued2005-12
Cita de ítemdc.identifier.citationJOURNAL OF THE CHILEAN CHEMICAL SOCIETY, V.: 50, issue: 4, p.: 647-650, DEC 2005en
Identifierdc.identifier.issn0717-9324
Identifierdc.identifier.urihttps://repositorio.uchile.cl/handle/2250/120613
Abstractdc.description.abstractThe catalysis of the hydroesterification and hydroformylation-acetalization of 1-hexene by rhodium(I), cis-[Rh(CO)2(amine)2](PF6) complexes (amine = pyridine, 2-picoline, 3-picoline, 4-picoline, 3,5-lutidine or 2,6-lutidine) dissolved in 10 mL of ethanol or 10 mL of 80% aqueous ethanol, 0.4 mL (3 x 10-3 mol) of 1-hexene, [Rh] = 5 x 10-5 mol, 1-hexene/Rh = 64 under P(CO) = 0.9 atm at 100 °C for 4 h, is described in this work. The mayor products are ethyl-heptanoate, heptanal and 1,1-diethoxyheptane coming from the hydroesterification, hydroformylation reactions and the nucleophilic addition reaction of the ethanol over the formed heptanal, respectively. The reaction product distribution depends on the nature of the coordinate amine to the rhodium center.en
Patrocinadordc.description.sponsorshipThe authors thank the CDCH-UCV (PG: 03.12.4957.2002) and the FONACIT (S1-2002000260) for funding. The authors also gratefully acknowledge support from CYTED: Red V-D and Project V-9. SAM thanks FONDECYT (Project 1050168)
Lenguagedc.language.isoenen
Publisherdc.publisherSOCIEDAD CHILENA DE QUIMICAen
Keywordsdc.subjectCatalysisen
Títulodc.titleReppe Reaction Catalyzed by Soluble Carbonylrhodium Complexesen
Document typedc.typeArtículo de revista


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