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Authordc.contributor.authorParedes García, Verónica 
Authordc.contributor.authorVenegas Yazigi, Diego es_CL
Authordc.contributor.authorLatorre, Ramón es_CL
Authordc.contributor.authorSpodine Spiridonova, Evgenia es_CL
Admission datedc.date.accessioned2009-06-08T13:13:43Z
Available datedc.date.available2009-06-08T13:13:43Z
Publication datedc.date.issued2006-06-19
Cita de ítemdc.identifier.citationPOLYHEDRON Volume: 25 Issue: 9 Pages: 2026-2032 Published: JUN 19 2006en
Identifierdc.identifier.issn0277-5387
Identifierdc.identifier.urihttp://repositorio.uchile.cl/handle/2250/120662
Abstractdc.description.abstractMixed valence dinuclear iron(II,III) complexes of the type [Fe2L2(H2O)(4)](NO3)(H2O)(3), where L is the dianion of a Schiff base ligand derived from alpha-amino acids (glycine and L-isolecine) and 5-bromosalicylaldehyde, have been prepared and characterised using different spectroscopic methods, magnetic susceptibility, conductivity, and electrochemical measurements. The mixed valence iron complexes can be described as hexacoordinated species, in which the metal ion is surrounded by water molecules, the salicylidenimine ligand and two bridging carboxylate groups. The presence of bromine as a substituent in the salicylaldehyde ring stabilises the mixed valence species.en
Lenguagedc.language.isoenen
Publisherdc.publisherPERGAMON-ELSEVIER SCIENCE LTDen
Keywordsdc.subjectIRON-OXO PROTEINSen
Títulodc.titleElectronic properties of mixed valence iron(II,III) dinuclear complexes with carboxylate bridgesen
Document typedc.typeArtículo de revistaen


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