| Author | dc.contributor.author | Larrazábal Rojas, Guillermo | es_CL |
| Author | dc.contributor.author | Parada Aliste, José | es_CL |
| Author | dc.contributor.author | Decinti Weiss, Emilio | |
| Admission date | dc.date.accessioned | 2009-08-26T11:41:58Z | |
| Available date | dc.date.available | 2009-08-26T11:41:58Z | |
| Publication date | dc.date.issued | 1999-03 | |
| Cita de ítem | dc.identifier.citation | BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA 44(1): 25-34 | en |
| Identifier | dc.identifier.issn | 0366-1644 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/120783 | |
| Abstract | dc.description.abstract | The Delta-Lambda isomerization of partially resolved [Ni(1,10-phen)(2)(S-aa)](+) systems, where Saa is S-phenylalaninate, S-isoleucinate, S-leucinate, S-valinate, or S-alaninate, has been studied at 15, 20 and 25 degrees C in methanol as solvent. Kinetic parameters have been obtained by means of optical rotation measurements. The first-order rate constants for the isomerization process follow the order S-leu > S-ala > S-phe > S-ileu > S-val, whereas Delta H double dagger and Delta S double dagger are in the sequence S-phe > S-ala > S-val > S-ileu > S-leu. These results are discussed in relation to the possible influences of intramolecular noncovalent interactions on the activation parameters. | en |
| Lenguage | dc.language.iso | en | en |
| Publisher | dc.publisher | SOCIEDAD CHILENA DE QUIMICA | en |
| Keywords | dc.subject | Nickel | en |
| Título | dc.title | Isomerization studies of Delta,Lambda-[Ni(1,10-phen)(2)(S-aa)](+) systems | en |
| Document type | dc.type | Artículo de revista | |
