| Author | dc.contributor.author | Spodine Spiridonova, Evgenia | |
| Author | dc.contributor.author | Atria Salas, Ana María | es_CL |
| Author | dc.contributor.author | Valenzuela Pedevila, Jorge | es_CL |
| Author | dc.contributor.author | Jalocha, J. | es_CL |
| Author | dc.contributor.author | Manzur Saffie, Jorge | es_CL |
| Author | dc.contributor.author | García, A. M. | es_CL |
| Author | dc.contributor.author | Garland, María Teresa | es_CL |
| Author | dc.contributor.author | Peña, Octavio | es_CL |
| Author | dc.contributor.author | Saillard, J. Y. | es_CL |
| Admission date | dc.date.accessioned | 2011-07-25T12:58:16Z | |
| Available date | dc.date.available | 2011-07-25T12:58:16Z | |
| Publication date | dc.date.issued | 1999-09-07 | |
| Cita de ítem | dc.identifier.citation | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS 17: 3029-3034 | es_CL |
| Identifier | dc.identifier.issn | 0300-9246 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/121468 | |
| General note | dc.description | Artículo de publicación ISI | es_CL |
| Abstract | dc.description.abstract | Three new copper(II) complexes with simple pyrazolate bridges have been prepared, [Cu-2(pz)(2)(dpa)(2)(H2O)Cl]Cl . H2O 1, [Cu-2(pz)(2)(phen)(2)Cl-2]. 2C(2)H(5)OH 2 and [Cu-2(pz)(phen)(2)Cl-3]. 2H(2)O 3 (Hpz = pyrazole, dpa = di(2-pyridyl)amine, phen = 1,10-phenanthroline) and their crystal and molecular structures determined. The copper centres in the binuclear cation in 1 have a square pyramidal geometry at Cu1 and a distorted octahedral geometry at Cu2. The neutral complexes 2 and 3 have the copper atoms in a distorted square pyramidal geometry. Complexes 1 and 2 are bibridged by pyrazolate while 3 is monobridged by this ligand. Variable temperature magnetic studies on all three complexes indicate the existence of antiferromagnetic exchange phenomena (-2J = 191, 169, 42 cm(-1) for 1, 2 and 3 respectively). Extended Huckel calculations showed a HOMO/LUMO gap which is in agreement with the experimental data. | es_CL |
| Lenguage | dc.language.iso | en | es_CL |
| Publisher | dc.publisher | ROYAL SOC CHEMISTRY | es_CL |
| Keywords | dc.subject | SCHIFF-BASE LIGAND | es_CL |
| Título | dc.title | Magnetic properties of dinuclear copper(II) complexes with simple pyrazolate bridges | es_CL |
| Document type | dc.type | Artículo de revista | |
