Show simple item record

Authordc.contributor.authorVega, Andrés 
Authordc.contributor.authorCalvo Pérez, Víctor es_CL
Authordc.contributor.authorSpodine Spiridonova, Evgenia es_CL
Authordc.contributor.authorZárate, Antonio es_CL
Authordc.contributor.authorFuenzalida Escobar, Víctor es_CL
Authordc.contributor.authorSaillard, Jean-Yves es_CL
Admission datedc.date.accessioned2013-12-31T13:48:35Z
Available datedc.date.available2013-12-31T13:48:35Z
Publication datedc.date.issued2002
Cita de ítemdc.identifier.citationInorganic Chemistry, Vol. 41, No. 13, 2002en_US
Identifierdc.identifier.urihttps://repositorio.uchile.cl/handle/2250/121695
Abstractdc.description.abstractThe reaction of the organometallic carboxylic acid HOOCCCHCo2(CO)6 with copper(II) methoxide leads to a new inorganometallic cluster; Cu3{í2-(CCHCo2(CO)6)}3. This cluster has a triangular core of copper(I) centers surrounded by three CCHCo2(CO)6 fragments. The structure of the cluster has short Cu-Cu and Cu-Co distances (average 2.500 and 2.540 Å, respectively). DFT calculations provide a rationalization of the peculiar bonding in this cluster.en_US
Patrocinadordc.description.sponsorshipFONDECYT (Grants 1980896, 2990093, and 4000027), FONDAP (Grant 11980002), and the French- Chilean CNRS/CONICYT program (PICS 922).en_US
Lenguagedc.language.isoenen_US
Type of licensedc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile*
Link to Licensedc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/*
Títulodc.titleA Novel Copper Cobalt Inorganometallic Cluster. Synthesis, Structure and Bonding Analysis of Cu3{í2-(CCHCo2(CO)6)}3en_US
Document typedc.typeArtículo de revistaen_US


Files in this item

Icon

This item appears in the following Collection(s)

Show simple item record

Attribution-NonCommercial-NoDerivs 3.0 Chile
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile