A Novel Copper Cobalt Inorganometallic Cluster. Synthesis, Structure and Bonding Analysis of Cu3{í2-(CCHCo2(CO)6)}3
| Author | dc.contributor.author | Vega, Andrés | |
| Author | dc.contributor.author | Calvo Pérez, Víctor | es_CL |
| Author | dc.contributor.author | Spodine Spiridonova, Evgenia | es_CL |
| Author | dc.contributor.author | Zárate, Antonio | es_CL |
| Author | dc.contributor.author | Fuenzalida Escobar, Víctor | es_CL |
| Author | dc.contributor.author | Saillard, Jean-Yves | es_CL |
| Admission date | dc.date.accessioned | 2013-12-31T13:48:35Z | |
| Available date | dc.date.available | 2013-12-31T13:48:35Z | |
| Publication date | dc.date.issued | 2002 | |
| Cita de ítem | dc.identifier.citation | Inorganic Chemistry, Vol. 41, No. 13, 2002 | en_US |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/121695 | |
| Abstract | dc.description.abstract | The reaction of the organometallic carboxylic acid HOOCCCHCo2(CO)6 with copper(II) methoxide leads to a new inorganometallic cluster; Cu3{í2-(CCHCo2(CO)6)}3. This cluster has a triangular core of copper(I) centers surrounded by three CCHCo2(CO)6 fragments. The structure of the cluster has short Cu-Cu and Cu-Co distances (average 2.500 and 2.540 Å, respectively). DFT calculations provide a rationalization of the peculiar bonding in this cluster. | en_US |
| Patrocinador | dc.description.sponsorship | FONDECYT (Grants 1980896, 2990093, and 4000027), FONDAP (Grant 11980002), and the French- Chilean CNRS/CONICYT program (PICS 922). | en_US |
| Lenguage | dc.language.iso | en | en_US |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | * |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | * |
| Título | dc.title | A Novel Copper Cobalt Inorganometallic Cluster. Synthesis, Structure and Bonding Analysis of Cu3{í2-(CCHCo2(CO)6)}3 | en_US |
| Document type | dc.type | Artículo de revista |
Files in this item
This item appears in the following Collection(s)
-
Artículos de revistas
Artículos de revistas
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile