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Organometallic Schiff bases derived from 5-nitrothiophene and 5-nitrofurane: Synthesis, crystallographic, electrochemical, ESR and antiTrypanosoma cruzi studies
Autor | dc.contributor.author | Arancibia, Rodrigo | |
Autor | dc.contributor.author | Klahn, A. Hugo | es_CL |
Autor | dc.contributor.author | Buono Core, Gonzalo E. | es_CL |
Autor | dc.contributor.author | Contreras, Daniel | es_CL |
Autor | dc.contributor.author | Barriga, Germán | es_CL |
Autor | dc.contributor.author | Olea Azar, Claudio | es_CL |
Autor | dc.contributor.author | Lapier, Michel | es_CL |
Autor | dc.contributor.author | Maya Arango, Juan | es_CL |
Autor | dc.contributor.author | Ibañez, Andrés | es_CL |
Autor | dc.contributor.author | Garland, María Teresa | es_CL |
Fecha ingreso | dc.date.accessioned | 2014-01-10T13:48:13Z | |
Fecha disponible | dc.date.available | 2014-01-10T13:48:13Z | |
Fecha de publicación | dc.date.issued | 2013 | |
Cita de ítem | dc.identifier.citation | Journal of Organometallic Chemistry 743 (2013) 49e54 | en_US |
Identificador | dc.identifier.other | DOI: 10.1016/j.jorganchem.2013.06.014 | |
Identificador | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/121738 | |
Nota general | dc.description | Artículo de publicación de ISI | en_US |
Resumen | dc.description.abstract | In the search for new therapeutic tools for the treatment of American trypanosomiasis, a series of novel ferrocene and cyrhetrene imine compounds, derived from 5-nitro-heterocycles, were designed, synthesized and characterized. The 1H and 13C NMR spectra indicated that these compounds adopted an anti-(E) conformation in solution, and this was confirmed by X-ray crystallography for one of the complexes (NT2). To study the relationship between the physicalechemical properties of N-iminyl substituents of nitrofurfuryl and nitrothienyl groups and their antitrypanosomal activity, we have carried out cyclic voltammetry and electron spin resonance studies of a series of organometallic imine compounds. The results demonstrated that the electronic properties of the side chain of the 5-nitroheterocyclic compound could be correlated to its trypanocidal effect. | en_US |
Idioma | dc.language.iso | en | en_US |
Publicador | dc.publisher | Elsevier | en_US |
Tipo de licencia | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | * |
Link a Licencia | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | * |
Palabras claves | dc.subject | Cyrhretrenylimines | en_US |
Título | dc.title | Organometallic Schiff bases derived from 5-nitrothiophene and 5-nitrofurane: Synthesis, crystallographic, electrochemical, ESR and antiTrypanosoma cruzi studies | en_US |
Tipo de documento | dc.type | Artículo de revista |
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