Remote regio- and stereocontrol by the sulfinyl group: Diels–Alder reaction of sulfinyl dienols and 8,8-dimethylnaphthalene-1,4,5(8H)-trione
Author
dc.contributor.author
Almodovar, Iriux
Author
dc.contributor.author
Cardona, Wilson
es_CL
Author
dc.contributor.author
Delgado Castro, Tomás
es_CL
Author
dc.contributor.author
Zapata Torres, Gerald Amilcar
es_CL
Author
dc.contributor.author
Caroli Rezende, Marcos
es_CL
Author
dc.contributor.author
Araya Maturana, Ramiro
es_CL
Author
dc.contributor.author
Maestro, M. Carmen
es_CL
Author
dc.contributor.author
García Ruano, José L.
es_CL
Admission date
dc.date.accessioned
2014-03-12T20:36:14Z
Available date
dc.date.available
2014-03-12T20:36:14Z
Publication date
dc.date.issued
2013
Cita de ítem
dc.identifier.citation
Tetrahedron: Asymmetry 24 (2013) 56–61
en_US
Identifier
dc.identifier.other
doi10.1016/j.tetasy.2012.11.017
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/121855
General note
dc.description
Artículo de publicación ISI
en_US
Abstract
dc.description.abstract
Diels–Alder cycloaddition of 8,8-dimethylnaphthalene-1,4,5(8H)-trione with diastereomeric hydroxysulfinyldienes
proceeded with high yields and good p-facial and regioselectivities. The hydroxysulfoxide
moiety controls the regio- and stereoselectivities, through hydrogen bonds in the suggested transition
state.