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Disodium nickel bis(sulfate) tetrahydrate: a nickel astrakanite

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2006-09
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Díaz de Vivar, Enriqueta
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Disodium nickel bis(sulfate) tetrahydrate: a nickel astrakanite
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Author
  • Díaz de Vivar, Enriqueta;
  • Baggio, Sergio;
  • Garland, María Teresa;
  • Baggio, Ricardo;
Abstract
The title compound, [Na2Ni(SO4)(2)(H2O)(4)] or Ni astrakanite, is part of an isostructural family containing the Mg (the original astrakanite mineral), Zn and Co species. The very regular NiO(H2O)(4)O(SO4)(2) octahedra lie at centers of symmetry, while the rather distorted NaO(H2O)(2)O(SO4)(4) octahedra are at general positions, linked into a three-dimensional network by the bridging water molecules and fully coordinated sulfate groups.
Identifier
URI: https://repositorio.uchile.cl/handle/2250/124827
ISSN: 1600-5368
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ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE Volume: 62 Pages: I196-I198 Part: Part 9 Published: SEP 2006
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