Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source
| Author | dc.contributor.author | Moya, S. A. | |
| Author | dc.contributor.author | Negrete Vergara, C. | |
| Author | dc.contributor.author | Brown, K. | |
| Author | dc.contributor.author | Artigas, V. | |
| Author | dc.contributor.author | Fuentealba, M. | |
| Author | dc.contributor.author | Guerchais, V. | |
| Author | dc.contributor.author | Aguirre, P. | |
| Admission date | dc.date.accessioned | 2018-05-14T17:40:04Z | |
| Available date | dc.date.available | 2018-05-14T17:40:04Z | |
| Publication date | dc.date.issued | 2017 | |
| Cita de ítem | dc.identifier.citation | Catalysis Communications 99 (2017) 150–153 | es_ES |
| Identifier | dc.identifier.other | http://dx.doi.org/10.1016/j.catcom.2017.04.026 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/147732 | |
| Abstract | dc.description.abstract | Ruthenium complexes containing phosphorus-nitrogen, pincer-type (NPN) ligands show high activities and selectivities in the transfer hydrogenation of N-benzylideneaniline using propan-2-ol as the hydrogen source. Such is the case of complexes RuCl2PPh3(PPh(NHPy)2) (1) and RuCl2PPh3(PPh(NHPyMe)2) (2) which also show TOFs 5989 h−1 and 5928 h−1, respectively. These remarkable results were obtained after only 10 min of reaction using a 1000/1 substrate/catalyst ratio. | es_ES |
| Patrocinador | dc.description.sponsorship | ECOS-CONICYT, Action C14E02 / Fondecyt-Chile, 1160505 | es_ES |
| Lenguage | dc.language.iso | en | es_ES |
| Publisher | dc.publisher | Elsevier | es_ES |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | * |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | * |
| Source | dc.source | Catalysis Communications | es_ES |
| Keywords | dc.subject | Hydrogenation catalysis | es_ES |
| Keywords | dc.subject | Hydrogenation propan-2-ol | es_ES |
| Keywords | dc.subject | Ruthenium catalysts | es_ES |
| Título | dc.title | Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source | es_ES |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | tjn | es_ES |
| Indexation | uchile.index | Artículo de publicación ISI | es_ES |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile