Facile and scalable one step method for amination of graphene using Leuckart Reaction
Author
dc.contributor.author
Aguilar Bolados, Héctor
Author
dc.contributor.author
Vargas Astudillo, Daniela Rocío
Author
dc.contributor.author
Yazdani-Pedram Zobeiri, Mehrdad
Author
dc.contributor.author
Acosta Villavicencio, Gabriela
Author
dc.contributor.author
Fuentealba, Pablo
Author
dc.contributor.author
Contreras Cid, Ahirton
Author
dc.contributor.author
Verdejo, Raquel
Author
dc.contributor.author
López Manchado, Miguel
Admission date
dc.date.accessioned
2018-07-09T14:49:58Z
Available date
dc.date.available
2018-07-09T14:49:58Z
Publication date
dc.date.issued
2017
Cita de ítem
dc.identifier.citation
Chem. Mater. 2017, 29, 6698−6705
es_ES
Identifier
dc.identifier.other
10.1021/acs.chemmater.7b01438
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/149655
Abstract
dc.description.abstract
A very simple method of reductive amination, based on the Leuckart reaction, is reported. This method enables not only the reduction of graphite oxide but also results in reduced graphene oxide functionalized with amine groups, where the amination degree is 3.2 at. % as determined by XPS. The dominant nitrogen functional group was primary amine, but pyridines and lactam groups were also observed. It was found that the amino-functionalized reduced graphene oxide is a semi-metallic material because of the lack of band gap, unlike the graphite oxide that presented a band gap of 2.16 eV.
es_ES
Patrocinador
dc.description.sponsorship
National Commission for Scientific and Technological Research (CONICYT), Chile
3170104
Vice Presidency of Research and Development (VID), Universidad de Chile, Chile, under Project Enlaces
Spanish Ministry of Science and Innovation (MICINN), Spain
MAT2013-48107-C3