Formation of radical anions by electrochemical reduction of nitroimidazoles in aprotic solvents and mixed solvent
| Author | dc.contributor.author | Norambuena, E. | |
| Author | dc.contributor.author | Olea Azar, Claudio | |
| Admission date | dc.date.accessioned | 2018-12-20T14:11:12Z | |
| Available date | dc.date.available | 2018-12-20T14:11:12Z | |
| Publication date | dc.date.issued | 1996 | |
| Cita de ítem | dc.identifier.citation | Spectroscopy Letters, (1996) 29: 1367-1379 | |
| Identifier | dc.identifier.issn | 00387010 | |
| Identifier | dc.identifier.other | 10.1080/00387019608007129 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/154502 | |
| Abstract | dc.description.abstract | The EPR spectra of radicals obtained by electrohytical reduction of 2-nitroimidazole and 4-nitroimidazole were measured in mixed solvents. The behavior of the nitrogen coupling constants with the solvent composition is discussed in terms of equilibria between radicals in different solvents. The equilibrium constants of the DMSO/water system were determinated. Molecular orbital calculations in the frame of LCAO-HMO method account correctly for the spin distribution of both compounds investigated. | |
| Lenguage | dc.language.iso | en | |
| Publisher | dc.publisher | Marcel Dekker Inc. | |
| Publisher | dc.publisher | Taylor & Francis | |
| Source | dc.source | Spectroscopy Letters | |
| Keywords | dc.subject | Cyclic voltammetry | |
| Keywords | dc.subject | EPR | |
| Keywords | dc.subject | Nitroimidazoles | |
| Keywords | dc.subject | Radical anions | |
| Título | dc.title | Formation of radical anions by electrochemical reduction of nitroimidazoles in aprotic solvents and mixed solvent | |
| Document type | dc.type | Artículo de revista | |
| dcterms.accessRights | dcterms.accessRights | Acceso a solo metadatos | |
| Cataloguer | uchile.catalogador | apc | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| Indexation | uchile.index | Artículo de publicación ISI | |
| uchile.cosecha | uchile.cosecha | SI |
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