Substituent effects in frontier orbitals of cyclic hydroxamic acids

Author	dc.contributor.author	Weiss López, Boris
Author	dc.contributor.author	Bravo, Héctor R.
Admission date	dc.date.accessioned	2018-12-20T15:04:41Z
Available date	dc.date.available	2018-12-20T15:04:41Z
Publication date	dc.date.issued	1994
Cita de ítem	dc.identifier.citation	Heterocycles, Volumen 38, Issue 1, 2018, Pages 9-16
Identifier	dc.identifier.issn	03855414
Identifier	dc.identifier.uri	https://repositorio.uchile.cl/handle/2250/157590
Abstract	dc.description.abstract	AM1 full geometry optimization of seven substituted cyclic hydroxamic acids (Hx) was performed. A qualitative correlation between Elumo vs Hammett's σP was observed. The reactivity of these 7-substituted Hx with hard nucleophiles seems to follow basic principles of frontier orbitals theory. Experimental support was obtained from the reaction of six Hx with 2-methoxyethylamine. © 1994.
Lenguage	dc.language.iso	en
Type of license	dc.rights	Attribution-NonCommercial-NoDerivs 3.0 Chile
Link to License	dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/cl/
Source	dc.source	Heterocycles
Keywords	dc.subject	Analytical Chemistry
Keywords	dc.subject	Pharmacology
Keywords	dc.subject	Organic Chemistry
Título	dc.title	Substituent effects in frontier orbitals of cyclic hydroxamic acids
Document type	dc.type	Artículo de revista
Cataloguer	uchile.catalogador	SCOPUS
Indexation	uchile.index	Artículo de publicación SCOPUS
uchile.cosecha	uchile.cosecha	SI

Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile